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Equal volumes of two monoatomic gases, A...

Equal volumes of two monoatomic gases, `A,B` at the same temperature and pressure are mixed.The ratio of specific heats`(C_(p)//C_(v))`of the mixture will be

A

`0.83`

B

`1.50`

C

`3.3`

D

`1.67`

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The correct Answer is:
To find the ratio of specific heats \( \frac{C_p}{C_v} \) for the mixture of two monoatomic gases \( A \) and \( B \), we can follow these steps: ### Step 1: Understand the specific heats of monoatomic gases For a monoatomic ideal gas: - The specific heat at constant volume \( C_v \) is given by: \[ C_v = \frac{3}{2} R \] - The specific heat at constant pressure \( C_p \) is given by: \[ C_p = C_v + R = \frac{3}{2} R + R = \frac{5}{2} R \] ### Step 2: Calculate the specific heats for the mixture Since both gases \( A \) and \( B \) are monoatomic and are mixed in equal volumes: - The specific heat at constant volume \( C_v \) for the mixture can be calculated as: \[ C_v (\text{mixture}) = \frac{C_{vA} + C_{vB}}{2} = \frac{\frac{3}{2} R + \frac{3}{2} R}{2} = \frac{3}{2} R \] - The specific heat at constant pressure \( C_p \) for the mixture can be calculated as: \[ C_p (\text{mixture}) = \frac{C_{pA} + C_{pB}}{2} = \frac{\frac{5}{2} R + \frac{5}{2} R}{2} = \frac{5}{2} R \] ### Step 3: Calculate the ratio \( \frac{C_p}{C_v} \) Now, we can find the ratio of specific heats for the mixture: \[ \frac{C_p}{C_v} = \frac{\frac{5}{2} R}{\frac{3}{2} R} = \frac{5}{3} \] ### Step 4: Conclusion Thus, the ratio of specific heats \( \frac{C_p}{C_v} \) for the mixture of the two monoatomic gases \( A \) and \( B \) is: \[ \frac{C_p}{C_v} = \frac{5}{3} \approx 1.67 \]
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