Home
Class 12
CHEMISTRY
If K1 is the equilibrium constant at tem...

If `K_1` is the equilibrium constant at temperature `T_1 and K_2` is the equilibrium constant at temperature `T_2 and` If `T_2 gt T_1` and reaction is endothermic then

A

`K_2 lt K_1`

B

`K_2 = K_1`

C

`K_2 gt K_1`

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the relationship between the equilibrium constants \( K_1 \) and \( K_2 \) at two different temperatures \( T_1 \) and \( T_2 \) for an endothermic reaction. ### Step-by-Step Solution: 1. **Understanding Endothermic Reactions**: - An endothermic reaction absorbs heat, which means that the enthalpy change (\( \Delta H \)) for the reaction is positive. 2. **Using the Van 't Hoff Equation**: - The Van 't Hoff equation relates the change in the equilibrium constant with temperature: \[ \log \frac{K_2}{K_1} = \frac{\Delta H}{2.303R} \left( \frac{1}{T_1} - \frac{1}{T_2} \right) \] - Here, \( R \) is the universal gas constant, which is always positive. 3. **Analyzing the Temperature Condition**: - We are given that \( T_2 > T_1 \). Therefore, \( \frac{1}{T_1} > \frac{1}{T_2} \). This means that the term \( \left( \frac{1}{T_1} - \frac{1}{T_2} \right) \) is positive. 4. **Substituting into the Van 't Hoff Equation**: - Since \( \Delta H \) is positive (for endothermic reactions) and \( R \) is positive, the entire right-hand side of the equation is positive: \[ \log \frac{K_2}{K_1} > 0 \] 5. **Interpreting the Result**: - If \( \log \frac{K_2}{K_1} > 0 \), it implies that: \[ K_2 > K_1 \] 6. **Conclusion**: - Therefore, for an endothermic reaction where \( T_2 > T_1 \), the equilibrium constant at the higher temperature \( K_2 \) is greater than the equilibrium constant at the lower temperature \( K_1 \). ### Final Answer: - The correct option is that \( K_2 \) is greater than \( K_1 \).
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION -A)|50 Videos
  • EQUILIBRIUM

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION -B)|35 Videos
  • EQUILIBRIUM

    AAKASH INSTITUTE ENGLISH|Exercise TRY YOURSELF|52 Videos
  • ENVIRONMENTAL CHEMISTRY

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION-D) (Assertion - Reason Type Questions)|4 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section-D) Assertion-Reason Type Question|15 Videos

Similar Questions

Explore conceptually related problems

For a given exothermic reaction , K_P and K_p' are the equilibrium constant at temperature T_1 and T_2 respectively .Assuming that heat of reaction is constant in temperature range between T_1 and T_2 , it is readly observed that

If K_(1)= Rate constant at temperature T_(1) and k_(2) rate constant at temperature T_(2) for a first order reaction, then which of the following relation is correct ?

Van't Hoff's equation for a chemical reaction under equilibrium is given by standard reaction enthalpy at temperature T and K is the equilibrium constant . Predict how K will vary with temperature for an exothermic

If 'O' is at equilibrium then the values of the tension T_(1) and T_2 respectively.

If the solution boils at a temperature T_1 and solvent at a temperature T_2 the elevation of boiling point is given by:

A rod of length l and cross sectional area A has a variable conductivity given by K=alphaT , where alpha is a positive constant T is temperatures in Kelvin. Two ends of the rod are maintained at temperatures T_1 and T_2(T_1gtT_2) . Heat current flowing through the rod will be

A rod of length l and cross-section area A has a variable thermal conductivity given by K = alpha T, where alpha is a positive constant and T is temperature in kelvin. Two ends of the rod are maintained at temperature T_(1) and T_(2) (T_(1)gtT_(2)) . Heat current flowing through the rod will be

Seven rods A, B, C, D, E, F and G are joined as shown in figure. All the rods have equal cross-sectional area A and length l. The thermal conductivities of the rods are K_(A)=K_(C)=K_(0) , K_(B)=K_(D)=2K_(0) , K_(E)=3K_(0) , K_(F)=4K_(0) and K_(G)=5K_(0) . The rod E is kept at a constant temperature T_(1) and the rod G is kept at a constant temperature T_(2) (T_(2)gtT_(1)) . (a) Show that the rod F has a uniform temperature T=(T_(1)+2T_(2))//3 . (b) Find the rate of heat flowing from the source which maintains the temperature T_(2) .

For A+BhArrC+D , the equilibrium constant is K_(1) and for C+DhArrA+B , the equilibrium constant is K_(2) . The correct relation between K_(1) and K_(2) is

A copper block of mass 'm' at temperature 'T_(1)' is kept in the open atmosphere at temperature 'T_(2)' where T_(2) gt T_(1) . The variation of entropy of the copper block with time is best illustrated by

AAKASH INSTITUTE ENGLISH-EQUILIBRIUM-EXERCISE
  1. Choose the correct statement

    Text Solution

    |

  2. In which of the following equilibrium , change in pressure will not a...

    Text Solution

    |

  3. If K1 is the equilibrium constant at temperature T1 and K2 is the equi...

    Text Solution

    |

  4. If Ar is added to the equilibrium N2(g) +3H2(g) hArr 2NH3 at constant ...

    Text Solution

    |

  5. In which of the following case pH is greater than 7 ?

    Text Solution

    |

  6. The compound that is not a Lewis acid is

    Text Solution

    |

  7. The pH of a solution obtained by mixing 100 ml of 0.2 M CH3COOH with 1...

    Text Solution

    |

  8. With increases in temperature pH of pure water

    Text Solution

    |

  9. The pH of a solution increased from 3 to 6. Its [H^(o+)] will be

    Text Solution

    |

  10. Which pair will show common ion effect ?

    Text Solution

    |

  11. The pH of solution at 25^@C which has twice as many hydroxide ion as i...

    Text Solution

    |

  12. Fear or excitement, generally cause one to breathe rapidly and it resu...

    Text Solution

    |

  13. Which of the following can act as a lewis acid ?

    Text Solution

    |

  14. Which of the following is an Arrhenius base ?

    Text Solution

    |

  15. For a MX2 type salt if K(sp) is solubility product, then solubility ...

    Text Solution

    |

  16. The compound whose 0.1 M solution is basic is

    Text Solution

    |

  17. The correct order of increasing solubility of AgCI in (A) water (B...

    Text Solution

    |

  18. The solubility of AgCI is

    Text Solution

    |

  19. If the Kb value in the hydrolysis reaction B^(+)+H2O hArr BOH +H^+ ...

    Text Solution

    |

  20. Which of the following increasing order of pH of 0.1 M solution of the...

    Text Solution

    |