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For reaction 2A+B hArr 2C, K=x Equilib...

For reaction `2A+B hArr 2C, K=x`
Equilibrium constant for `C hArr A+1//2 B` will be

A

x

B

`x/2`

C

`1/sqrtx`

D

`sqrtx`

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant for the reaction: \[ C \rightleftharpoons A + \frac{1}{2} B \] given that the equilibrium constant for the reaction: \[ 2A + B \rightleftharpoons 2C \] is \( K = x \). ### Step-by-Step Solution: 1. **Write the equilibrium expression for the first reaction:** The equilibrium constant \( K \) for the reaction \( 2A + B \rightleftharpoons 2C \) is given by: \[ K = \frac{[C]^2}{[A]^2[B]} \] Since we know \( K = x \), we can write: \[ x = \frac{[C]^2}{[A]^2[B]} \] 2. **Write the equilibrium expression for the second reaction:** For the reaction \( C \rightleftharpoons A + \frac{1}{2} B \), the equilibrium constant \( K' \) is given by: \[ K' = \frac{[A][B]^{1/2}}{[C]} \] 3. **Relate the two reactions:** The second reaction can be derived from the first reaction by reversing it and adjusting the stoichiometry. When we reverse the first reaction, we get: \[ 2C \rightleftharpoons 2A + B \] The equilibrium constant for this reversed reaction is: \[ K_{reverse} = \frac{1}{K} = \frac{1}{x} \] 4. **Adjust for stoichiometry:** The reaction \( 2C \rightleftharpoons 2A + B \) can be divided by 2 to match the stoichiometry of the second reaction: \[ C \rightleftharpoons A + \frac{1}{2} B \] When we divide the reaction by 2, the equilibrium constant for the new reaction is: \[ K' = \sqrt{K_{reverse}} = \sqrt{\frac{1}{x}} = \frac{1}{\sqrt{x}} \] 5. **Final Result:** Thus, the equilibrium constant \( K' \) for the reaction \( C \rightleftharpoons A + \frac{1}{2} B \) is: \[ K' = \frac{1}{\sqrt{x}} \] ### Conclusion: The equilibrium constant for the reaction \( C \rightleftharpoons A + \frac{1}{2} B \) is \( \frac{1}{\sqrt{x}} \).
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