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For the reaction, I(2)(aq)hArrI(2)" (o...

For the reaction,
`I_(2)(aq)hArrI_(2)" (oil), Equilibrium constant is K"_(1).`
`I_(2)"(oil)"hArrI_(2)"(ether), Equilibrium constant is K"_(2).`
`I_(2)(aq)hArrI_(2)"(ether), Equilibrium constant is K"_(3).`
The reaction between `K_(1), K_(2), K_(3)` is

A

`K_3=K_1+K_2`

B

`K_3=K_1K_2`

C

`K_3=K_1//K_2`

D

`K_3=K_2//K_1`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to establish the relationships between the equilibrium constants \( K_1 \), \( K_2 \), and \( K_3 \) based on the given reactions. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants**: - The first reaction is: \[ I_2(aq) \rightleftharpoons I_2(oil) \quad \text{with equilibrium constant } K_1 \] - The second reaction is: \[ I_2(oil) \rightleftharpoons I_2(ether) \quad \text{with equilibrium constant } K_2 \] - The third reaction is: \[ I_2(aq) \rightleftharpoons I_2(ether) \quad \text{with equilibrium constant } K_3 \] 2. **Combine the First Two Reactions**: - We can add the first and second reactions: \[ I_2(aq) \rightleftharpoons I_2(oil) \quad (K_1) \] \[ I_2(oil) \rightleftharpoons I_2(ether) \quad (K_2) \] - When we add these two reactions, the \( I_2(oil) \) cancels out: \[ I_2(aq) \rightleftharpoons I_2(ether) \] 3. **Relate the Equilibrium Constants**: - According to the principle of equilibrium constants, when two reactions are added, their equilibrium constants multiply: \[ K_3 = K_1 \times K_2 \] 4. **Conclusion**: - Therefore, the relationship between the equilibrium constants is: \[ K_3 = K_1 \times K_2 \] ### Final Answer: The relationship between the equilibrium constants is: \[ K_3 = K_1 \times K_2 \]
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