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A : Increasing the concentration of H2 w...

A : Increasing the concentration of `H_2` will increases
magnitude of equilibrium constant of the reaction
`H_2 +I_2 hArr 2HI`
R: Value of `K_c` depends upon the concentration of reactants and products taken.

A

If both Assertion & Reason are true and the reason in the corret explanation of the assertion, then mark

B

If both assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark

C

If Assertion is true statement but Reason is false then mark

D

If both Assertion and Reason are false statements , then mark

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided in the context of the equilibrium constant (Kc) for the reaction: \[ H_2 + I_2 \rightleftharpoons 2HI \] ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that increasing the concentration of \( H_2 \) will increase the magnitude of the equilibrium constant \( K_c \). - The equilibrium constant \( K_c \) for the reaction is given by the formula: \[ K_c = \frac{[HI]^2}{[H_2][I_2]} \] - Here, \( [HI] \), \( [H_2] \), and \( [I_2] \) represent the molar concentrations of the respective substances at equilibrium. 2. **Analyzing the Effect of Concentration on \( K_c \)**: - According to Le Chatelier's principle, if the concentration of a reactant (in this case, \( H_2 \)) is increased, the system will shift to the right to counteract the change, producing more products (HI). - However, this does not affect the value of \( K_c \) itself; it only affects the concentrations of the reactants and products until a new equilibrium is established. 3. **Conclusion about the Assertion**: - The assertion is **false** because increasing the concentration of \( H_2 \) does not increase the magnitude of \( K_c \); it only shifts the equilibrium position. 4. **Understanding the Reason (R)**: - The reason states that the value of \( K_c \) depends upon the concentration of reactants and products taken. - This statement is also **false** because the equilibrium constant \( K_c \) is a fixed value at a given temperature and does not depend on the concentrations of reactants and products. It is determined solely by the nature of the reaction and the temperature. 5. **Final Conclusion**: - Since both the assertion and the reason are false, the correct answer to the question is that both A and R are false. ### Final Answer: Both assertion (A) and reason (R) are false.
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