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A : For H2CO3 K(a1) lt K(a2). R : H2CO...

A : For `H_2CO_3 K_(a_1) lt K_(a_2)`.
R : `H_2CO_3` is weaker acid than `HCO_3^-`

A

If both Assertion & Reason are true and the reason in the corret explanation of the assertion, then mark

B

If both assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark

C

If Assertion is true statement but Reason is false then mark

D

If both Assertion and Reason are false statements , then mark

Text Solution

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The correct Answer is:
To solve the question, we need to analyze the assertion (A) and the reason (R) provided: ### Assertion (A): For \( H_2CO_3 \), \( K_{a_1} < K_{a_2} \). ### Reason (R): \( H_2CO_3 \) is a weaker acid than \( HCO_3^- \). ### Step-by-step Solution: 1. **Understanding the Dissociation of Carbonic Acid (\( H_2CO_3 \))**: - Carbonic acid (\( H_2CO_3 \)) is a diprotic acid, meaning it can donate two protons (H⁺). - The first dissociation can be represented as: \[ H_2CO_3 \rightleftharpoons H^+ + HCO_3^- \] This dissociation constant is denoted as \( K_{a_1} \). 2. **Second Dissociation of Bicarbonate (\( HCO_3^- \))**: - The second dissociation of bicarbonate is: \[ HCO_3^- \rightleftharpoons H^+ + CO_3^{2-} \] This dissociation constant is denoted as \( K_{a_2} \). 3. **Comparing \( K_{a_1} \) and \( K_{a_2} \)**: - For diprotic acids, the first dissociation constant (\( K_{a_1} \)) is usually greater than the second dissociation constant (\( K_{a_2} \)) because the first proton is generally more easily lost than the second. - Therefore, we can conclude that: \[ K_{a_1} > K_{a_2} \] - This contradicts the assertion \( K_{a_1} < K_{a_2} \). 4. **Analyzing the Acidity**: - The strength of an acid is determined by its ability to donate protons. - \( H_2CO_3 \) can donate two protons, while \( HCO_3^- \) can only donate one. - Thus, \( H_2CO_3 \) is a stronger acid than \( HCO_3^- \). 5. **Conclusion**: - Both the assertion (A) and the reason (R) are false. - Therefore, the correct answer is that both the assertion and reason are false. ### Final Answer: Both assertion and reason are false.
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