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A : Oxidation number of carbon in HCN is...

A : Oxidation number of carbon in HCN is +4.
R : Oxidation state and valency is same for carbon.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the oxidation number of carbon in HCN (hydrogen cyanide) is +4. - To verify this, we need to determine the oxidation state of carbon in HCN. 2. **Assigning Oxidation States**: - In HCN, we have: - Hydrogen (H) typically has an oxidation state of +1. - Nitrogen (N) typically has an oxidation state of -3. - Let the oxidation state of carbon (C) be represented as \( x \). 3. **Setting Up the Equation**: - The sum of oxidation states in a neutral molecule must equal zero. Therefore, we can write the equation: \[ +1 + x - 3 = 0 \] - Simplifying this equation gives: \[ x - 2 = 0 \quad \Rightarrow \quad x = +2 \] - Thus, the oxidation state of carbon in HCN is +2, not +4. 4. **Conclusion for Assertion (A)**: - Since the assertion states that the oxidation number of carbon in HCN is +4, and we found it to be +2, the assertion is **false**. 5. **Understanding the Reason (R)**: - The reason states that the oxidation state and valency are the same for carbon. - Valency refers to the number of electrons an atom can lose, gain, or share during a chemical reaction. For carbon, the valency is 4 (as it can form four bonds). 6. **Comparing Oxidation State and Valency**: - We have established that the oxidation state of carbon in HCN is +2. - Since the valency of carbon is 4 and its oxidation state in this case is +2, they are not the same. 7. **Conclusion for Reason (R)**: - Therefore, the reason that states oxidation state and valency are the same for carbon is also **false**. 8. **Final Conclusion**: - Both the assertion (A) and the reason (R) are false. ### Final Answer: - Both Assertion (A) and Reason (R) are false.
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