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A : Equivalent weight of KMnO(4) in acid...

A : Equivalent weight of `KMnO_(4)` in acidic medium is `M/5`.
R : In acidic medium 1 mol of `MnO_(4)""^(-)` gains 5 electron.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason statements about the equivalent weight of KMnO4 in acidic medium, we will break down the concepts step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the equivalent weight of KMnO4 in acidic medium is \( \frac{M}{5} \), where \( M \) is the molar mass of KMnO4. 2. **Understanding the Reason**: - The reason states that in acidic medium, 1 mole of \( \text{MnO}_4^- \) gains 5 electrons. 3. **Analyzing the Reaction**: - In acidic medium, the reduction reaction of \( \text{MnO}_4^- \) can be represented as: \[ \text{MnO}_4^- + 8 \text{H}^+ + 5 \text{e}^- \rightarrow \text{Mn}^{2+} + 4 \text{H}_2\text{O} \] - Here, \( \text{MnO}_4^- \) is reduced to \( \text{Mn}^{2+} \). 4. **Calculating Oxidation States**: - The oxidation state of manganese in \( \text{MnO}_4^- \) is +7 (calculated as follows): \[ x + 4(-2) = -1 \implies x - 8 = -1 \implies x = +7 \] - In \( \text{Mn}^{2+} \), the oxidation state is +2. 5. **Determining the Change in Oxidation State**: - The change in oxidation state for manganese is: \[ +7 \text{ (in } \text{MnO}_4^-\text{)} \rightarrow +2 \text{ (in } \text{Mn}^{2+}\text{)} \] - This indicates that manganese gains 5 electrons during the reduction. 6. **Finding the Equivalent Weight**: - The equivalent weight is defined as: \[ \text{Equivalent Weight} = \frac{\text{Molar Mass}}{n} \] - Here, \( n \) is the number of electrons gained or lost, which is 5 in this case. - Therefore, the equivalent weight of KMnO4 in acidic medium is: \[ \text{Equivalent Weight} = \frac{M}{5} \] 7. **Conclusion**: - Both the assertion and the reason are true. The reason correctly explains the assertion. ### Final Answer: Both the assertion and reason are true, and the reason is the correct explanation of the assertion.
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