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A : The number of spheres are equal to t...

A : The number of spheres are equal to the number of octahedral voids as well as tetrahedral void.
R : Octahedral void and tetrahedral void has equal size.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided in the statement. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the number of spheres (atoms) is equal to the number of octahedral voids as well as the number of tetrahedral voids. - In a crystal lattice, the number of octahedral voids is equal to the number of atoms (Z) present in the unit cell. - However, the number of tetrahedral voids is twice the number of atoms in the unit cell, which means it is equal to 2Z. 2. **Analyzing the Assertion**: - If we assume Z = 10 (as an example), then: - Number of octahedral voids = Z = 10 - Number of tetrahedral voids = 2Z = 20 - Therefore, the assertion that the number of spheres is equal to the number of octahedral voids and tetrahedral voids is **false**. 3. **Understanding the Reason (R)**: - The reason states that octahedral voids and tetrahedral voids have equal size. - To evaluate this, we need to look at the radius ratio for both types of voids: - The radius ratio for tetrahedral voids lies between 0.225 and 0.414. - The radius ratio for octahedral voids lies between 0.414 and 0.732. 4. **Analyzing the Reason**: - Since the radius ratios for tetrahedral and octahedral voids are different, it indicates that the sizes of these voids are also different. - Thus, the reason that octahedral voids and tetrahedral voids have equal size is **false**. 5. **Conclusion**: - Both the assertion (A) and the reason (R) are false. - Therefore, the correct answer is that both the assertion and reason are false. ### Final Answer: Both assertion (A) and reason (R) are false.
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AAKASH INSTITUTE ENGLISH-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
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  2. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

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  3. A : The number of spheres are equal to the number of octahedral voids ...

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  4. A : In Schottky defect, density of crystal decreases. R : Equal nu...

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  5. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

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  6. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

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  7. A : Glass belongs to the category of covalent network solid. R : U...

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  8. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

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  9. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

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  10. A : In molecular solids the lattice points are occupied by the atoms o...

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  11. A : Silicon is insulator at 0 K but semiconductor at room temperature....

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  12. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

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  13. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

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  14. A : All crystals of same substance possess the same elements of symmet...

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  15. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

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  16. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

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  17. A : The coordination number of ionic compound depends upon radius rati...

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  18. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

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  19. A : ccp is more efficient than hcp. R : Packing fraction is differe...

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  20. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

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