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A : The coordination number of ionic com...

A : The coordination number of ionic compound depends upon radius ratio.
R : Higher the coordination number higher will be stability.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false then mark (3)

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will analyze the assertion and reason step by step. ### Step 1: Understand the Assertion The assertion states that "the coordination number of ionic compounds depends upon the radius ratio." - **Explanation**: The radius ratio is defined as the ratio of the radius of the cation (R_c) to the radius of the anion (R_a). The coordination number refers to the number of nearest neighbor ions surrounding a central ion in a crystal lattice. For ionic compounds, this coordination number is influenced by the size of the ions involved. ### Step 2: Analyze the Radius Ratio The radius ratio can be expressed as: \[ \text{Radius Ratio} = \frac{R_c}{R_a} \] - **Observation**: As the radius ratio increases, the coordination number also tends to increase. For example, a radius ratio of 0.225 corresponds to a coordination number of 4 (tetrahedral), while a radius ratio of 0.414 corresponds to a coordination number of 6 (octahedral). ### Step 3: Understand the Reason The reason states that "higher the coordination number, higher will be stability." - **Explanation**: This statement is also true. A higher coordination number means that more anions can surround a cation, and vice versa. This close packing leads to a more stable ionic structure because the electrostatic interactions between the cations and anions are maximized. ### Step 4: Determine the Relationship Between Assertion and Reason Now we need to determine if the reason provided is a correct explanation of the assertion. - **Analysis**: While both statements are true, the reason does not directly explain why the coordination number depends on the radius ratio. The assertion is about the dependency of coordination number on radius ratio, while the reason discusses stability related to coordination number. ### Conclusion Based on the analysis: - Both the assertion and reason are true. - However, the reason does not correctly explain the assertion. Thus, the correct answer is: **Option 2**: Both assertion and reason are true, but the reason is not the correct explanation of the assertion. ---
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AAKASH INSTITUTE ENGLISH-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
  1. A : In NaCl structure, the interionic distance is a/2 (a = Unit cell e...

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  2. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

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  3. A : The number of spheres are equal to the number of octahedral voids ...

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  4. A : In Schottky defect, density of crystal decreases. R : Equal nu...

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  5. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

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  6. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

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  7. A : Glass belongs to the category of covalent network solid. R : U...

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  8. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

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  9. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

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  10. A : In molecular solids the lattice points are occupied by the atoms o...

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  11. A : Silicon is insulator at 0 K but semiconductor at room temperature....

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  12. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

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  13. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

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  14. A : All crystals of same substance possess the same elements of symmet...

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  15. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

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  16. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

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  17. A : The coordination number of ionic compound depends upon radius rati...

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  18. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

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  19. A : ccp is more efficient than hcp. R : Packing fraction is differe...

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  20. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

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