1 mole glucose is added to 1 L of water `K_(b)(H_(2)O)=0.512" K kg mole"^(-1)` boiling point of solution will be
1 mole glucose is added to 1 L of water `K_(b)(H_(2)O)=0.512" K kg mole"^(-1)` boiling point of solution will be
A
`373.512^@C`
B
`100.512^@C`
C
`99.488^@C`
D
`372.488^@C`
Text Solution
AI Generated Solution
The correct Answer is:
To find the boiling point of the solution when 1 mole of glucose is added to 1 L of water, we can follow these steps:
### Step 1: Understand the Concept of Boiling Point Elevation
The boiling point of a solution is elevated when a solute is added to a solvent. This phenomenon is described by the formula:
\[
\Delta T_b = K_b \times m
\]
where:
- \(\Delta T_b\) = boiling point elevation
- \(K_b\) = ebullioscopic constant of the solvent (water in this case)
- \(m\) = molality of the solution
### Step 2: Calculate the Molality of the Solution
Molality (m) is defined as the number of moles of solute per kilogram of solvent. In this case, we have:
- Moles of glucose = 1 mole
- Mass of water = 1 L of water = 1000 g = 1 kg (since the density of water is approximately 1 g/mL)
Thus, the molality \(m\) can be calculated as:
\[
m = \frac{\text{moles of solute}}{\text{mass of solvent in kg}} = \frac{1 \text{ mole}}{1 \text{ kg}} = 1 \text{ mol/kg}
\]
### Step 3: Use the Boiling Point Elevation Formula
Now, we can substitute the values into the boiling point elevation formula:
\[
\Delta T_b = K_b \times m = 0.512 \, \text{K kg mole}^{-1} \times 1 \, \text{mol/kg} = 0.512 \, \text{K}
\]
### Step 4: Calculate the New Boiling Point
The normal boiling point of water is 100 °C (or 373.15 K). Therefore, the new boiling point of the solution can be calculated as:
\[
\text{New boiling point} = 100 \, °C + \Delta T_b = 100 \, °C + 0.512 \, °C = 100.512 \, °C
\]
### Final Answer
The boiling point of the solution will be **100.512 °C**.
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Complete the following statements by selecting the correct alternative from the choices given : An aqueous solution of urea freezes at - 0.186^(@)C, K_(f) for water = 1.86 K kg. mol^(-1),K_(b) for water = 0.512 "K kg mol"^(-1) . The boiling point of urea solution will be :
Properties such as boiling point, freezing point and vapour, pressure of a pure solvent change Propeties such as boiling point, freezing point and vapour, pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 Given Freezing point depression constant of water (K_(f)^("water"))=1.86 K kg "mol"^(-1) Freezing point depression constant of ethanol (K_(f)^("ethanol"))=2.0 K kg "mol"^(-1) Boiling point elevation constant of water (K_(b)^("water"))=0.52 kg "mol"^(-1) Boiling point elevation constant of ethanol (K_(b)^("ethanol"))=1.2 kg "mol"^(-1) Standard freezing point of water =273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water =373 K tandard boiling point of ethanol =351.5 K Vapour pressure of pure water =32.8 mmHg Vapour presure of pure ethanol =40g Hg Molecular weight of water =18 g"mol"^(-1) Molecules weight of ethanol =46 g "mol"^(-1) In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 The freezing point of the solution M is
Properties such as boiling point, freezing point and vapour, pressure of a pure solvent change Propeties such as boiling point, freezing point and vapour, pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 Given Freezing point depression constant of water (K_(f)^("water"))=1.86 K kg "mol"^(-1) Freezing point depression constant of ethanol (K_(f)^("ethanol"))=2.0 K kg "mol"^(-1) Boiling point elevation constant of water (K_(b)^("water"))=0.52 kg "mol"^(-1) Boiling point elevation constant of ethanol (K_(b)^("ethanol"))=1.2 kg "mol"^(-1) Standard freezing point of water =273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water =373 K tandard boiling point of ethanol =351.5 K Vapour pressure of pure water =32.8 mmHg Vapour presure of pure ethanol =40g Hg Molecular weight of water =18 g"mol"^(-1) Molecules weight of ethanol =46 g "mol"^(-1) In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 Given Freezing point depression constant of water (K_(f)^("water"))=1.86 K kg "mol"^(-1) Freezing point depression constant of ethanol (K_(f)^("ethanol"))=2.0 K kg "mol"^(-1) Boiling point elevation constant of water (K_(b)^("water"))=0.52 kg "mol"^(-1) Boiling point elevation constant of ethanol (K_(b)^("ethanol"))=1.2 kg "mol"^(-1) Standard freezing point of water =273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water =373 K tandard boiling point of ethanol =351.5 K Vapour pressure of pure water =32.8 mmHg Vapour presure of pure ethanol =40g Hg Molecular weight of water =18 g"mol"^(-1) Molecules weight of ethanol =46 g "mol"^(-1) In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. The vapour pressure of the solution M is
Properties such as boiling point, freezing point and vapour, pressure of a pure solvent change Propeties such as boiling point, freezing point and vapour, pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 Given Freezing point depression constant of water (K_(f)^("water"))=1.86 K kg "mol"^(-1) Freezing point depression constant of ethanol (K_(f)^("ethanol"))=2.0 K kg "mol"^(-1) Boiling point elevation constant of water (K_(b)^("water"))=0.52 kg "mol"^(-1) Boiling point elevation constant of ethanol (K_(b)^("ethanol"))=1.2 kg "mol"^(-1) Standard freezing point of water =273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water =373 K tandard boiling point of ethanol =351.5 K Vapour pressure of pure water =32.8 mmHg Vapour presure of pure ethanol =40g Hg Molecular weight of water =18 g"mol"^(-1) Molecules weight of ethanol =46 g "mol"^(-1) In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles. A solution M is prepared by mixing athanol and water. The mole fraction of ethanol in the mixture is 0.9 Given Freezing point depression constant of water (K_(f)^("water"))=1.86 K kg "mol"^(-1) Freezing point depression constant of ethanol (K_(f)^("ethanol"))=2.0 K kg "mol"^(-1) Boiling point elevation constant of water (K_(b)^("water"))=0.52 kg "mol"^(-1) Boiling point elevation constant of ethanol (K_(b)^("ethanol"))=1.2 kg "mol"^(-1) Standard freezing point of water =273 K Standard freezing point of ethanol = 155.7 K Standard boiling point of water =373 K tandard boiling point of ethanol =351.5 K Vapour pressure of pure water =32.8 mmHg Vapour presure of pure ethanol =40g Hg Molecular weight of water =18 g"mol"^(-1) Molecules weight of ethanol =46 g "mol"^(-1) In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative. Water is added to the solution M such that the fraction of water in the solution becomes 0.9 . The boiling point of this solutions is
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