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If DeltaG for the reaction is A^(+) + B^...

If `DeltaG` for the reaction is `A^(+) + B^(-) rarr A^(2+) + B^(2-) ` is x, the `DeltaG` for the reaction is
`(1)/(2)A^(+) + (1)/(2)B^(-) rarr (1)/(2) A^(2+) + (1)/(2) B^(2-)` is

A

`(x)/(2)`

B

2x

C

`x^(2)`

D

`sqrtx`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reactions and their corresponding Gibbs free energy changes (ΔG). ### Step-by-Step Solution: 1. **Identify the Given Reaction and ΔG**: The first reaction is: \[ A^+ + B^- \rightarrow A^{2+} + B^{2-} \] The change in Gibbs free energy (ΔG) for this reaction is given as \( x \). 2. **Understand the Relationship Between ΔG and Electrons**: For any redox reaction, the relationship between ΔG and the cell potential (E_cell) is given by: \[ \Delta G = -nFE_{cell} \] where \( n \) is the number of moles of electrons transferred, \( F \) is Faraday's constant, and \( E_{cell} \) is the cell potential. 3. **Determine the Number of Electrons Transferred in the First Reaction**: In the first reaction: - \( A^+ \) is oxidized to \( A^{2+} \) (loses 1 electron). - \( B^- \) is reduced to \( B^{2-} \) (gains 1 electron). Therefore, the total number of electrons transferred \( n \) in this reaction is 1. 4. **Write the Expression for ΔG of the First Reaction**: From the relationship, we have: \[ \Delta G_1 = -1 \cdot F \cdot E_{cell} = x \] 5. **Analyze the Second Reaction**: The second reaction is: \[ \frac{1}{2}A^+ + \frac{1}{2}B^- \rightarrow \frac{1}{2}A^{2+} + \frac{1}{2}B^{2-} \] Here, we need to determine the number of electrons transferred. 6. **Determine the Number of Electrons Transferred in the Second Reaction**: In this case: - \( \frac{1}{2} A^+ \) loses \( \frac{1}{2} \) electron. - \( \frac{1}{2} B^- \) gains \( \frac{1}{2} \) electron. Thus, the total number of electrons transferred \( n \) in this reaction is \( \frac{1}{2} \). 7. **Write the Expression for ΔG of the Second Reaction**: Using the same relationship: \[ \Delta G_2 = -\frac{1}{2} \cdot F \cdot E_{cell} \] 8. **Relate ΔG of the Second Reaction to the First**: Since we know that \( \Delta G_1 = x \), we can express \( \Delta G_2 \) in terms of \( x \): \[ \Delta G_2 = -\frac{1}{2} \cdot F \cdot E_{cell} = \frac{1}{2} \Delta G_1 = \frac{1}{2} x \] 9. **Final Answer**: Therefore, the change in Gibbs free energy for the second reaction is: \[ \Delta G_2 = \frac{x}{2} \] ### Conclusion: The answer is \( \frac{x}{2} \).
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