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Select the equivalent conductivity of 1....

Select the equivalent conductivity of `1.0 M H_(2)SO_(4)`, if its conductivity is `0.26 ohm^(-1) cm^(-1)`:

A

`1.3 xx 10^(2) S cm^(2) eq^(-1)`

B

`1.6 xx 10^(2) S cm^(-1)`

C

`13S cm^(2) mol^(-1)`

D

`1.3 xx 10^(3) S cm^(2) mol^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equivalent conductivity of 1.0 M \( H_2SO_4 \) given its conductivity, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Given Values:** - Conductivity (\( \kappa \)) of \( H_2SO_4 \) = 0.26 \( \Omega^{-1} \, \text{cm}^{-1} \) - Molarity (C) of \( H_2SO_4 \) = 1.0 M 2. **Determine the n-factor of \( H_2SO_4 \):** - \( H_2SO_4 \) is a diprotic acid, meaning it can donate two protons (H\(^+\)). Therefore, the n-factor = 2. 3. **Calculate Normality (N):** - Normality (N) is calculated as: \[ N = n \times C \] - Here, \( n = 2 \) and \( C = 1.0 \, \text{M} \): \[ N = 2 \times 1.0 = 2.0 \, \text{N} \] 4. **Use the Formula for Equivalent Conductivity (\( \Lambda \)):** - The formula relating conductivity to equivalent conductivity is: \[ \Lambda = \frac{\kappa \times 1000}{N} \] - Where \( \kappa \) is in \( \Omega^{-1} \, \text{cm}^{-1} \) and \( N \) is in equivalents per liter. The factor of 1000 is used to convert liters to milliliters. 5. **Substitute the Values:** - Substitute \( \kappa = 0.26 \, \Omega^{-1} \, \text{cm}^{-1} \) and \( N = 2.0 \): \[ \Lambda = \frac{0.26 \times 1000}{2.0} \] 6. **Calculate Equivalent Conductivity:** - Performing the calculation: \[ \Lambda = \frac{260}{2} = 130 \, \text{S cm}^2 \, \text{equivalent}^{-1} \] - This can be expressed in scientific notation as: \[ \Lambda = 1.3 \times 10^2 \, \text{S cm}^2 \, \text{equivalent}^{-1} \] 7. **Final Answer:** - The equivalent conductivity of \( 1.0 \, M \, H_2SO_4 \) is \( 1.3 \times 10^2 \, \text{S cm}^2 \, \text{equivalent}^{-1} \). ### Conclusion: The correct option is \( 1.3 \times 10^2 \, \text{S cm}^2 \, \text{equivalent}^{-1} \).
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