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The resistance of 0.0025M solution of K(...

The resistance of 0.0025M solution of `K_(2)SO_(4)` is 326ohm. The specific conductance of the solution, if cell constant is 4.

A

`4.997 xx 10^(-4)`

B

`5.99 xx 10^(-7)`

C

`6.99 xx 10^(-4)`

D

`1.20 xx 10^(-2)`

Text Solution

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The correct Answer is:
To find the specific conductance (also known as conductivity) of a 0.0025 M solution of K₂SO₄ with a resistance of 326 ohms and a cell constant of 4, we can follow these steps: ### Step 1: Understand the relationship between resistance and conductivity The specific conductance (κ) is related to resistance (R) and the cell constant (k) by the formula: \[ \kappa = \frac{k}{R} \] where: - \( \kappa \) is the specific conductance (in S/m), - \( k \) is the cell constant (in m⁻), - \( R \) is the resistance (in ohms). ### Step 2: Substitute the given values into the formula From the problem, we have: - Resistance \( R = 326 \, \Omega \) - Cell constant \( k = 4 \) Now, substituting these values into the formula: \[ \kappa = \frac{4}{326} \] ### Step 3: Calculate the specific conductance Now, perform the calculation: \[ \kappa = \frac{4}{326} \approx 0.01227 \, \text{S/m} \] ### Step 4: Convert to scientific notation To express this value in scientific notation: \[ 0.01227 = 1.227 \times 10^{-2} \, \text{S/m} \] Rounding to two significant figures gives: \[ \kappa \approx 1.20 \times 10^{-2} \, \text{S/m} \] ### Conclusion Thus, the specific conductance of the solution is: \[ \kappa = 1.20 \times 10^{-2} \, \text{S/m} \] ### Final Answer The correct option is option number 4: \( 1.20 \times 10^{-2} \). ---
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