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A: Electrolysis of molten calcium hydrid...

A: Electrolysis of molten calcium hydride produces hydrogen gas at the cathode.
R: Hydrogen in calcium hydride is present as `H^(+)` ion.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false, then mark (3)

D

If both Assertion and Reason are false statements then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the electrolysis of molten calcium hydride, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Electrolysis of molten calcium hydride produces hydrogen gas at the cathode." - In electrolysis, reduction occurs at the cathode and oxidation occurs at the anode. 2. **Electrolysis of Calcium Hydride**: - When molten calcium hydride (CaH₂) undergoes electrolysis, it dissociates into calcium ions (Ca²⁺) and hydride ions (H⁻). - The reactions occurring during electrolysis are: - At the **cathode**: Reduction occurs. The calcium ions (Ca²⁺) gain electrons to form solid calcium (Ca). \[ \text{Ca}^{2+} + 2e^- \rightarrow \text{Ca} \] - At the **anode**: Oxidation occurs. The hydride ions (H⁻) lose electrons to form hydrogen gas (H₂). \[ 2\text{H}^- \rightarrow \text{H}_2 + 2e^- \] 3. **Analyzing the Assertion**: - From the reactions above, we see that hydrogen gas is produced at the anode, not at the cathode. Therefore, the assertion is **false**. 4. **Understanding the Reason**: - The reason states that "Hydrogen in calcium hydride is present as H⁺ ion." - In reality, in calcium hydride, hydrogen is present as hydride ions (H⁻), not as H⁺ ions. Therefore, this statement is also **false**. 5. **Conclusion**: - Since both the assertion and the reason are false, the correct answer is option 4: "Both assertion and reason are false statements."
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