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On heating oxalic acid with H2SO4 , we...

On heating oxalic acid with `H_2SO_4` , we get

A

`H_2CO_3`

B

`CO_2 and O_2 `

C

`CO_2 and CO `

D

`H_2CO_3 + CO_2 + O_2 `

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the products formed when oxalic acid is heated with concentrated sulfuric acid (H₂SO₄), we can follow these steps: ### Step 1: Understand the Reactants Oxalic acid (C₂H₂O₄) is a dicarboxylic acid. When it is heated, especially in the presence of a strong dehydrating agent like concentrated sulfuric acid, it undergoes decomposition. **Hint:** Identify the structure and formula of oxalic acid to understand its components. ### Step 2: Identify the Role of Sulfuric Acid Concentrated sulfuric acid is known to act as a dehydrating agent. This means it can remove water (H₂O) from the reactants during the reaction. **Hint:** Recall the properties of sulfuric acid and its behavior when mixed with organic compounds. ### Step 3: Write the Decomposition Reaction When oxalic acid is heated with sulfuric acid, it decomposes to form carbon dioxide (CO₂) and carbon monoxide (CO), along with water. The balanced reaction can be represented as: \[ \text{C}_2\text{H}_2\text{O}_4 \xrightarrow{\text{H}_2\text{SO}_4} \text{CO}_2 + \text{CO} + \text{H}_2\text{O} \] **Hint:** Consider the products of thermal decomposition reactions of organic acids. ### Step 4: Identify the Products From the decomposition reaction, we can see that the products formed are carbon dioxide (CO₂) and carbon monoxide (CO). **Hint:** Check the stoichiometry of the reaction to confirm the products formed. ### Step 5: Conclusion Thus, when oxalic acid is heated with concentrated sulfuric acid, the main products are carbon dioxide (CO₂) and carbon monoxide (CO). **Final Answer:** On heating oxalic acid with H₂SO₄, we get carbon dioxide (CO₂) and carbon monoxide (CO). ### Summary of the Solution Steps: 1. Identify the reactants (oxalic acid). 2. Understand the role of sulfuric acid as a dehydrating agent. 3. Write the decomposition reaction. 4. Identify the products formed. 5. Conclude with the final answer.
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