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Hybridisation of central N atom in N(2) ...

Hybridisation of central N atom in `N_(2) O` is

A

`sp`

B

`sp^(2)`

C

`sp^(3)`

D

sp & `sp^(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the hybridization of the central nitrogen atom in the molecule \( N_2O \), we can follow these steps: ### Step 1: Determine the Valence Electrons - **Nitrogen (N)** has an atomic number of 7, with the electron configuration of \( 1s^2 2s^2 2p^3 \). Therefore, nitrogen has 5 valence electrons. - **Oxygen (O)** has an atomic number of 8, with the electron configuration of \( 1s^2 2s^2 2p^4 \). Therefore, oxygen has 6 valence electrons. ### Step 2: Draw the Lewis Structure - In \( N_2O \), there are two nitrogen atoms and one oxygen atom. - The total number of valence electrons is \( 5 + 5 + 6 = 16 \) valence electrons. - To complete the octets, we can arrange the electrons as follows: - One nitrogen atom will form a triple bond with the other nitrogen atom (sharing three pairs of electrons). - The nitrogen atom that is bonded to oxygen will form a coordinate bond with oxygen, sharing one pair of electrons. ### Step 3: Identify the Bonds and Lone Pairs - The nitrogen that is bonded to oxygen will have: - 1 sigma bond with oxygen (from the coordinate bond). - 1 sigma bond with the other nitrogen atom. - 2 pi bonds with the other nitrogen atom. - This nitrogen atom will also have 1 lone pair of electrons. ### Step 4: Determine the Hybridization - The hybridization can be determined by the number of regions of electron density around the nitrogen atom: - 2 sigma bonds (1 with oxygen and 1 with nitrogen). - 1 lone pair. - This gives a total of 3 regions of electron density. ### Step 5: Identify the Hybridization Type - According to the VSEPR theory, if there are 2 regions of electron density, the hybridization is \( sp \). - If there are 3 regions of electron density, the hybridization is \( sp^2 \). - If there are 4 regions of electron density, the hybridization is \( sp^3 \). - In this case, since we have 3 regions of electron density (2 sigma bonds and 1 lone pair), the hybridization of the central nitrogen atom in \( N_2O \) is \( sp^2 \). ### Final Answer The hybridization of the central nitrogen atom in \( N_2O \) is \( sp \). ---
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