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Which of the following statements about ...

Which of the following statements about `H_(3) BO_(3)` is not correct ?

A

It has a layer structure in which planar `BO_(3)` units are joined by hydrogen bonds

B

It does not act as proton donor but acts as a Lewis acid by accepting hydroxyl ion

C

It is a strong tribasic acid

D

It is prepared by acidifying an aqueous solution of borax

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement about H₃BO₃ (Boric acid) is not correct, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement A: It has a layer structure in which planar BO₃ units are joined by hydrogen bonds.** - H₃BO₃ has a layered structure where the boron atoms are surrounded by three oxygen atoms, forming planar BO₃ units. These units are indeed linked together by hydrogen bonds. - **Conclusion:** This statement is correct. 2. **Statement B: It does not act as a proton donor but acts as a Lewis acid by accepting hydroxyl ions.** - Boric acid (H₃BO₃) does not donate protons (H⁺) like typical acids. Instead, it can accept hydroxyl ions (OH⁻) to form tetrahydroxyborate (B(OH)₄⁻), acting as a Lewis acid. - **Conclusion:** This statement is correct. 3. **Statement C: It is a strong tribasic acid.** - Although H₃BO₃ has three hydroxyl groups, it does not behave as a strong tribasic acid. Instead, it acts as a Lewis acid and accepts hydroxyl ions rather than donating protons. Therefore, it does not fully dissociate into three protons in solution. - **Conclusion:** This statement is incorrect. 4. **Statement D: It is prepared by acidifying an aqueous solution of borax.** - Borax (Na₂B₄O₇·10H₂O) can be converted to boric acid by treating it with an acid (like HCl) in an aqueous solution. This reaction is well-known and valid. - **Conclusion:** This statement is correct. ### Final Answer: The statement that is not correct about H₃BO₃ is **C: It is a strong tribasic acid.** ---
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