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A : In Diborane containing eight -B-H bo...

A : In Diborane containing eight -B-H bonds only four B-H bonds are on the plane .
R : Boron in `B_(2) H_(6)` is `sp^(2)` hybridised .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that in diborane (B₂H₆), which contains eight B-H bonds, only four B-H bonds are in the same plane. - To visualize this, we need to draw the structure of diborane. Diborane has a unique structure where two boron atoms are connected by two bridging hydrogen atoms and each boron is also bonded to two terminal hydrogen atoms. - In the structure, the four terminal B-H bonds lie in the same plane, while the two bridging B-H bonds are above and below this plane, making the overall geometry of diborane a three-dimensional shape. 2. **Conclusion on the Assertion**: - The assertion is correct because, indeed, only four of the B-H bonds are coplanar while the other four are oriented in a perpendicular manner to this plane. 3. **Understanding the Reason**: - The reason states that boron in B₂H₆ is sp² hybridized. - To determine the hybridization of boron in diborane, we need to consider the bonding and geometry. Each boron atom in diborane forms four bonds (two terminal B-H bonds and two bridging B-H bonds). - Since boron forms four equivalent bonds, it undergoes sp³ hybridization, not sp² hybridization. 4. **Conclusion on the Reason**: - The reason is incorrect because boron in B₂H₆ is sp³ hybridized due to the formation of four bonds. 5. **Final Conclusion**: - The assertion is correct, while the reason is incorrect. Therefore, the correct answer is that the assertion is true, and the reason is false. ### Summary: - **Assertion (A)**: True - **Reason (R)**: False
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