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A : All the oxides of boron family with ...

A : All the oxides of boron family with the general formula `M_(2) O_(3)` are basic .
R : From `B_(2) O_(3)` to `Tl_(2) O_(3)` basic character decreases .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the oxides of the boron family, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "All the oxides of the boron family with the general formula M₂O₃ are basic." - **Fact Check**: The oxides of the boron family (Group 13 elements) include B₂O₃, Al₂O₃, Ga₂O₃, In₂O₃, and Tl₂O₃. - **Nature of B₂O₃**: Boron oxide (B₂O₃) is known to be acidic in nature, as it reacts with water to form boric acid (H₃BO₃). - **Conclusion**: Since B₂O₃ is acidic, the assertion that all oxides of the boron family are basic is false. ### Step 2: Analyze the Reason The reason states that "From B₂O₃ to Tl₂O₃, basic character decreases." - **Fact Check**: As we move down the group from boron (B) to thallium (Tl), the basic character of the oxides actually increases. - **Basicity Trend**: - B₂O₃ is acidic. - Al₂O₃ and Ga₂O₃ are amphoteric (can act as both acids and bases). - In₂O₃ and Tl₂O₃ are basic. - **Conclusion**: The statement that basic character decreases from B₂O₃ to Tl₂O₃ is also false. ### Final Conclusion Both the assertion and the reason are false. Therefore, the correct answer is that both the assertion and reason are false. ### Summary of the Solution - Assertion: False (B₂O₃ is acidic, not basic) - Reason: False (Basic character increases from B₂O₃ to Tl₂O₃)
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