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A : CN^(-) is pseudohalide . R : (CN)(...

A : `CN^(-)` is pseudohalide .
R : `(CN)_(2)` is pseudohalogen .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion , then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion , then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze the assertion and reasoning provided, and determine their validity. ### Step-by-Step Solution: 1. **Understanding the Assertion:** - The assertion states that `CN^(-)` (cyanide ion) is a pseudohalide. - A pseudohalide is defined as a species that exhibits similar properties to halides. 2. **Characteristics of Pseudohalides:** - Pseudohalides must be univalent (having a valency of one). - They should form bonds with nitrogen. - They should form precipitates with silver ions (Ag+). 3. **Evaluating the Assertion:** - The cyanide ion `CN^(-)` is indeed univalent. - When `CN^(-)` reacts with `H^+`, it forms hydrogen cyanide (HCN). - When `CN^(-)` reacts with `Ag^+`, it forms silver cyanide (AgCN), which is a precipitate. - Therefore, the assertion that `CN^(-)` is a pseudohalide is true. 4. **Understanding the Reasoning:** - The reasoning states that `(CN)_(2)` (dicyanide) is a pseudohalogen. - Pseudohalogens are compounds that behave similarly to halogens and can form similar types of compounds. 5. **Evaluating the Reasoning:** - Dicyanide `(CN)_(2)` can be considered a pseudohalogen because it can form similar compounds and has properties akin to halogens. - Thus, the reasoning that `(CN)_(2)` is a pseudohalogen is also true. 6. **Conclusion:** - Both the assertion and reasoning are true. - However, the reasoning does not correctly explain why `CN^(-)` is a pseudohalide, as it focuses on a different compound. - Therefore, the correct answer is that both statements are true, but the reasoning is not the correct explanation of the assertion. ### Final Answer: Both A and R are true, but R is not the correct explanation of A.
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