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When molten NaCl is electrolysed by usin...

When molten NaCl is electrolysed by using inert electrode, the product obtained al cathode is

A

Na

B

`Cl_2`

C

`H_2`

D

Na Hg amalgam

Text Solution

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The correct Answer is:
To solve the question regarding the product obtained at the cathode when molten NaCl is electrolyzed using inert electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis is the process of chemical decomposition that occurs when an electric current is passed through an electrolyte, resulting in the movement of ions. 2. **Identifying the Electrolyte**: - In this case, the electrolyte is molten sodium chloride (NaCl). When NaCl is heated to a high temperature, it melts and dissociates into its constituent ions: sodium ions (Na⁺) and chloride ions (Cl⁻). 3. **Identifying the Electrodes**: - During electrolysis, there are two electrodes: the anode (positive electrode) and the cathode (negative electrode). Inert electrodes do not participate in the chemical reaction but provide a surface for the reactions to occur. 4. **Movement of Ions**: - The sodium ions (Na⁺), being cations, are attracted to the cathode (negative electrode). The chloride ions (Cl⁻), being anions, are attracted to the anode (positive electrode). 5. **Reduction at the Cathode**: - At the cathode, a reduction reaction occurs. The sodium ions (Na⁺) gain electrons (reduction) to form sodium metal (Na): \[ \text{Na}^+ + e^- \rightarrow \text{Na} \] 6. **Oxidation at the Anode**: - At the anode, the chloride ions (Cl⁻) lose electrons (oxidation) to form chlorine gas (Cl₂): \[ 2 \text{Cl}^- \rightarrow \text{Cl}_2 + 2e^- \] 7. **Conclusion**: - The product obtained at the cathode during the electrolysis of molten NaCl is sodium metal (Na). ### Final Answer: The product obtained at the cathode when molten NaCl is electrolyzed using inert electrodes is **sodium (Na)**.
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