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Ce(Z = 58) and Yb(Z = 70) exhibits stabl...

`Ce(Z = 58)` and `Yb(Z = 70)` exhibits stable +4 and 2 oxidation states respectively. This is because

A

`Ce^(4+)` and `Yb^(2+)`acquire `f^(7)` configuration

B

`Ce^(4+)` and `Yb^(2+)` acquire `f^(0)` configuration

C

`Ce^(4+)` and `Yb^(2+)` acquire `f_(o)` and `f^(14)` configuration

D

`Ce^(4+)` and `Yb^(2+)` acquire `f^(7)` and `f^(14)` configuration

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The correct Answer is:
To solve the question regarding why cerium (Ce) exhibits a stable +4 oxidation state and yttrium (Yb) exhibits a stable +2 oxidation state, we can follow these steps: ### Step 1: Determine the Electronic Configuration - **Cerium (Ce, Z = 58)** has the electronic configuration: \[ \text{Xe} \, 4f^1 \, 5d^1 \, 6s^2 \] - **Ytterbium (Yb, Z = 70)** has the electronic configuration: \[ \text{Xe} \, 4f^{14} \, 6s^2 \] ### Step 2: Analyze the Oxidation States - For **Cerium (Ce)** to achieve a +4 oxidation state, it loses 4 electrons: - The electrons lost come from the 6s and 5d orbitals: \[ \text{Ce}^{4+} \rightarrow \text{Xe} \, 4f^0 \, 5d^0 \, 6s^0 \] - This results in a configuration of \( 4f^0 \), which is stable because it has no electrons in the f-orbital. - For **Ytterbium (Yb)** to achieve a +2 oxidation state, it loses 2 electrons: - The electrons lost come from the 6s orbital: \[ \text{Yb}^{2+} \rightarrow \text{Xe} \, 4f^{14} \, 6s^0 \] - This results in a configuration of \( 4f^{14} \), which is stable because it is fully filled. ### Step 3: Stability of the Configurations - The stability of oxidation states is often associated with achieving noble gas configurations or stable electron configurations (like half-filled or fully filled subshells). - **Cerium (+4)** achieves a stable configuration of \( 4f^0 \) (empty f-orbital). - **Ytterbium (+2)** achieves a stable configuration of \( 4f^{14} \) (fully filled f-orbital). ### Conclusion - Thus, the reason why cerium exhibits a stable +4 oxidation state and yttrium exhibits a stable +2 oxidation state is that: - **Cerium (Ce) achieves a stable \( 4f^0 \) configuration.** - **Ytterbium (Yb) achieves a stable \( 4f^{14} \) configuration.** ### Final Answer The correct option is: **Cerium \( 4^+ \) acquires \( F^0 \) configuration and Ytterbium \( 2^+ \) acquires \( F^{14} \) configuration.** ---
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  3. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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