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General electronic configuration of lant...

General electronic configuration of lanthanides is

A

`(n - 2) f^(1- 14) (n-1) d^(0-1) ns^(2)`

B

`(n - 2) f^(10- 14) (n-1) d^(0-1) ns^(2)`

C

`(n - 2) f^(0- 14) (n-1) d^(10) ns^(2)`

D

`(n - 2) f^(0- 1) (n-1) f^(1-14) ns^(2)`

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The correct Answer is:
To determine the general electronic configuration of lanthanides, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Range of Lanthanides**: - Lanthanides are the elements with atomic numbers from 58 (Cerium) to 71 (Lutetium). This gives us a total of 14 elements. 2. **Determine the Period and Group**: - Lanthanides are located in the sixth period of the periodic table. They are also part of the f-block elements. 3. **Understand the Electron Filling Order**: - In lanthanides, the electrons fill the 4f subshell before the 5d subshell. This is due to the Aufbau principle, where electrons occupy the lowest energy orbitals first. 4. **General Electronic Configuration**: - The general electronic configuration for lanthanides can be expressed as: - \( [Xe] 6s^2 4f^{1-14} \) - Here, \( [Xe] \) represents the electron configuration of Xenon, which accounts for the filled inner shells. 5. **Include the Penultimate and Pre-Penultimate Shells**: - In addition to the 4f subshell, we must also consider the filled 5s and 5p subshells: - The complete configuration can be represented as: - \( [Xe] 6s^2 4f^{1-14} 5d^{0-1} \) - This indicates that the 5d subshell can have up to 1 electron. 6. **Final General Electronic Configuration**: - Therefore, the general electronic configuration of lanthanides can be summarized as: - \( n-2 f^{1-14} n-1 s^2 n-1 p^6 n-1 d^{0-1} \) - For lanthanides, this translates to: - \( 4f^{1-14} 5d^{0-1} 6s^2 6p^6 \) ### Conclusion: The correct general electronic configuration for lanthanides is: - **Option 1**: \( n-2 f^{1-14}, n-1 d^{0-1}, n-1 s^2, n-1 p^6 \)
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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