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Naming of Ligand [M(en)(2)]^(n+)starts w...

Naming of Ligand `[M(en)_(2)]^(n+)`starts with

A

Di

B

Bi

C

Bis

D

Any of these

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The correct way of naming Co in [CoCl_2(en)_2]^+ is __

The complex ion . [M(en)Br_(2)I_(2)]^(-1) , has two optical isomers. Their correct configurations are:

Total number of electrons donated by ligands to platinum ion in [Pt(en)_(2)Cl_(2)] is

Ligands are broadly classified into two classes classical and non-classical ligands, depending on their donor annd acceptor ability. Classical ligands form classical complexes while non-classical ligands form non-classical complex. Bonding mechanism in non-classical is called synergic bonding. Q. In compound [M(CO)_(n)]^(x) , the correct match for highest 'M-C' bond length for given M, n and z respectively:

Ligands are broadly classified into two classes classical and non-classical ligands, depending on their donor annd acceptor ability. Classical ligands form classical complexes while non-classical ligands form non-classical complex. Bonding mechanism in non-classical is called synergic bonding. Q. In compound [M(CO)_(n)]^(z) , the correct match for highest 'M-C' bond length for given M, n and z respectively:

Assertion : In a coordination entity [PtCl_(2)(en)_(2)]^(2+) only the cis-isomer shows optical activity . Reason : Optical isomerism is common in octahedral complexes involving didentate ligands .

Name of the following compounds (a) [Cr(en)_(2)CI_(2)]CI (b ) [Pt(Py)_(4)][PtCI_(4)]

Draw all the isomers (geometrical and optical) of: (i) [CoCl_(2)(en)_(2)]^(+) (ii) [Co(NH_(3))Cl(en)_(2)]^(2+) (iii) [Co(NH_(3))_(2)Cl_(2)(en)]^(+)

Draw one of the geometrical isomers of the complex [Pt(en)_(2)Cl]^(2+) which is optically inactive. Also write the name of this entity according to the IUPAC nomenclature.

AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
  1. Naming of Ligand [M(en)(2)]^(n+)starts with

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  2. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

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  3. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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