Home
Class 12
CHEMISTRY
If the value of C.F.S.E. for "NI" is Del...

 If the value of C.F.S.E. for "NI" is `Delta` then it is for Pd should be

A

`1.1Delta_(0)`

B

`0.5Delta_(0)`

C

`1.5Delta_(0)`

D

`2Delta_(0)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the crystal field stabilizing energy (C.F.S.E.) for palladium (Pd) in relation to nickel (Ni), we can follow these steps: ### Step 1: Understand the C.F.S.E. for Nickel The problem states that the C.F.S.E. for nickel is represented as `Δ`. This value is the splitting energy for the d-orbitals in the crystal field created by ligands surrounding the metal ion. ### Step 2: Identify the Position of Nickel and Palladium Nickel (Ni) is a 3d transition metal with an atomic number of 28, while palladium (Pd) is a 4d transition metal with an atomic number of 46. ### Step 3: Understand the Trend in Crystal Field Stabilization Energy As we move from the 3d series (like Ni) to the 4d series (like Pd), the C.F.S.E. tends to increase. The increase is typically around 50% when moving from one series to the next due to the increased effective nuclear charge and reduced shielding effect from inner electrons. ### Step 4: Calculate the C.F.S.E. for Palladium Given that the C.F.S.E. for Ni is `Δ`, we can express the C.F.S.E. for Pd as follows: - If the C.F.S.E. for Ni is `Δ`, then for Pd, it will be increased by 50%. - Therefore, the C.F.S.E. for Pd can be calculated as: \[ \text{C.F.S.E. for Pd} = \Delta + 0.5 \Delta = 1.5 \Delta \] ### Step 5: Conclusion Thus, the value of C.F.S.E. for palladium (Pd) is `1.5Δ`. ### Final Answer The C.F.S.E. for Pd should be `1.5Δ`. ---
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS AND ETHERS

    AAKASH INSTITUTE ENGLISH|Exercise Try yourself|5 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    AAKASH INSTITUTE ENGLISH|Exercise Exercise|40 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    AAKASH INSTITUTE ENGLISH|Exercise Try Yourself|5 Videos

Similar Questions

Explore conceptually related problems

Show that the sum of the three altitudes of a triangle is less than the sum of three sides of the triangle. GIVEN :triangle A B C in which A D_|_B C ,B E_|_A C and C F_|_A Bdot PROVE : A D+B E+C F < A B+B C+A C

If delta_0 of Ni^(2+) in presence of NH_3 is 100 KJ then that for Pd^(2+) will be

Fill in the blanks in the following so that each of the following statements is true. (i) Sides opposite to equal angles of a triangle are ....... (ii) Angle opposite to equal sides of a triangle are ....... (iii) In an equilateral triangle all angles are ....... (iv) In a A B C if /_A=/_C , then A B=\ ..... (v) If altitudes C E\ a n d\ B F of a triangle A B C are equal, then A B= ........ (vi) In an isosceles triangle A B C with A B=A C , if B D\ a n d\ C E are its altitudes, then B D is .......... C E . (vii) In right triangles A B C\ a n d\ D E F , if hypotenuse A B=E F and side A C=D E , then A B C\ ~= ....

Two triangles are congruent if two sides and the included angle of one are equal to the corresponding sides and the included angle of the other triangle. GIVEN : Two triangles A B C and D E F such that A B=D E ,A C=D F and /_A=/_D PROVE : A B C~= D E F Figure

Determine the values of equilibrium constant (K_(c)) and DeltaG^(@) for the reaction Ni(s)+2Ag^(+)(aq)rarrNi^(2+)(aq)+2Ag(s), E^(@)=1.05 V. ( "Given " 1F=96500"C mol"^(-1))

Statement-1 : If e^(itheta)=cos theta +isintheta and the value of e^(iA).e^(iB).e^(iC) is equal to -1, where A,B,C are the angles of a triangle. and Statement -2 : In any triangleABC , A + B +C = 180^(@)

Find the principal value of "c o s e c"^(-1)(-2) .

A variable point P on the ellipse of eccentricity e is joined to the foci S and S' . The eccentricity of the locus of incentre of the triangle PSS' is (A) sqrt((2e)/(1+e)) (B) sqrt(e/(1+e)) (C) sqrt((1-e)/(1+e)) (D) e/(2(1+e))

A D ,\ B E\ a n d\ C F , the altitudes of A B C are equal. Prove that A B C is an equilateral triangle.

A D ,\ B E\ a n d\ C F , the altitudes of A B C are equal. Prove that A B C is an equilateral triangle.

AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
  1. If the value of C.F.S.E. for "NI" is Delta then it is for Pd should be

    Text Solution

    |

  2. Assertion : Boiling point of p-nitrophenol is greater than that of o-n...

    Text Solution

    |

  3. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

    Text Solution

    |

  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

    Text Solution

    |

  5. A : In esterification reaction , HCOOH is the most reactive acid among...

    Text Solution

    |

  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

    Text Solution

    |

  7. Phenol is less acidic than........... .

    Text Solution

    |

  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

    Text Solution

    |

  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

    Text Solution

    |

  10. A : Grignard's reagent is prepared in the presence of ether . R :...

    Text Solution

    |

  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

    Text Solution

    |

  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

    Text Solution

    |

  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

    Text Solution

    |

  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

    Text Solution

    |

  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

    Text Solution

    |

  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

    Text Solution

    |

  17. A : In esterification reaction alcohol act as nucleophile . R : ...

    Text Solution

    |

  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

    Text Solution

    |

  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

    Text Solution

    |

  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

    Text Solution

    |

  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

    Text Solution

    |