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A: AI(2)(CH(3))(6) is a dimeric compound...

A: `AI_(2)(CH_(3))_(6)` is a dimeric compound and has Similar structure to diborane. R: `AI_(2)(CH_(3))_(6)` in a sigma bonded complex

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

) If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4)

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AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the compound \( \text{Al}_2(\text{CH}_3)_6 \), we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that \( \text{Al}_2(\text{CH}_3)_6 \) is a dimeric compound and has a similar structure to diborane. - **Dimeric Nature**: \( \text{Al}_2(\text{CH}_3)_6 \) is indeed a dimer of trimethyl aluminum \( (\text{Al(CH}_3)_3) \). This means that two trimethyl aluminum units combine to form the dimeric structure. - **Structural Similarity to Diborane**: Diborane \( (\text{B}_2\text{H}_6) \) has a structure characterized by three-center two-electron bonds. In \( \text{Al}_2(\text{CH}_3)_6 \), similar bonding occurs where aluminum atoms and carbon atoms from the methyl groups form three-center two-electron bonds, resembling the bonding in diborane. **Conclusion**: The assertion is true. ### Step 2: Analyze the Reason The reason states that \( \text{Al}_2(\text{CH}_3)_6 \) is a sigma bonded complex. - **Sigma Bonding**: In \( \text{Al}_2(\text{CH}_3)_6 \), all the bonds formed are single bonds (sigma bonds). There are no pi bonds present. The bonding involves end-to-end overlap of atomic orbitals, which is characteristic of sigma bonds. **Conclusion**: The reason is also true. ### Step 3: Determine the Relationship Between Assertion and Reason While both the assertion and reason are true, we need to determine if the reason correctly explains the assertion. - The assertion describes the structure and dimeric nature of \( \text{Al}_2(\text{CH}_3)_6 \) and its similarity to diborane. - The reason explains that it is a sigma bonded complex, which is a characteristic of the bonding but does not specifically explain why it is similar to diborane. **Conclusion**: The reason does not provide a correct explanation for the assertion. ### Final Answer Based on the analysis: - Both the assertion and reason are true. - The reason does not explain the assertion. Thus, the correct option is **Option 2**: Both assertion and reason are true, but the reason is not the correct explanation of the assertion. ---
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. Phenol is less acidic than........... .

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  14. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  15. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  16. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  17. A : In esterification reaction alcohol act as nucleophile . R : ...

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  18. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  19. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  20. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  21. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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