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Derive the structure of (i) 2-Chlorohexa...

Derive the structure of (i) 2-Chlorohexane, (ii) Pent-4-en-2-ol, (iii) 3- Nitrocyclohexene, (iv) Cyclohex-2-en-1-ol, (v) 6-Hydroxy- heptanal.

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(i) Pent-4-en-2-ol ‘Pent’ indicates that parent hydrocarbon contains 5 carbon atoms in the chain ‘en’ and ‘ol’ correspond to the functional groups C = C and -OH at carbon atoms 4 and 2 respectively. Thus, the structure is
`CH_(2)=CHCH_(2)CH(OH)CH_(3)`
(ii)Cyclohex-2-en-1 -ol ‘1-ol’ means that a -OH group is present at C - 1, OH is suffixed functional group and gets preference over C = C bond. Thus, the structure is
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AAKASH INSTITUTE ENGLISH-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -Assignment(Section-D)(Assertion - Reason Type Questions)
  1. Derive the structure of (i) 2-Chlorohexane, (ii) Pent-4-en-2-ol, (iii)...

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  2. A: CH(3)-CH-CH(3) has 6. hyperconjugative hydrogens while CH(3)-CH-CH(...

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  3. A : Addition of HCN in alkene is a type of electrophilic substitution ...

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  4. A: The IUPAC name of CH(2)=CH-C=CH is but-3-en-1-yne. R: The prior...

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  5. A: Allyl carbanion (CH(2)=CH-CH(2)""^(-)) is more stable than""^(-)CH...

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  6. A: The isomeric structural alcohols of molecular formula C(4)H(10)O ar...

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  7. A:The formation of.NaCbTduring preparation q? sodium extract will give...

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  8. A : Before testing of halogens, sodium extract must be boiled with con...

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  9. A : Glycerol decomposes at its boiling point. R : It can be purifie...

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  10. Orthonitrophenol is steam volatile but paranitrophenol is not because ...

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  11. (a). If both (A) and (R) are correct and (R) is the correct explanatio...

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  12. A : Phenol is less acidic than benzoic acid. R: Phenoxide has less...

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  13. A : C(2)H(5) -""^(+)CH —C(2)H(5) . is more stable than CH(3)-""^(+)CH-...

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  14. A : CH(3)— BH — CH(2) can not show resonance. R : Boron and carboc...

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  15. A: C(2)BrClFI can form 6 different geometrical isomers. R : Each o...

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  16. A: Phenol is more reactive than toluene towards S(E) reaction. R: ...

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