An organic compound does not reacts with Tollen's reagent but undergoes Baeyer Villiger oxidation. The compound is

Options

A. `CH-=C-CH_(2)COCH_(3)`
B.
C. `CH_(3)CHO`
D. `CH_(3)-underset(O)underset(||)(C)-CH_(3)`

Answer

To solve the problem, we need to analyze the characteristics of the organic compound based on the given tests: Tollen's reagent and Baeyer-Villiger oxidation.

### Step 1: Understand the Tests
- **Tollen's Reagent Test**: This test is used to identify aldehydes and terminal alkynes. A positive result indicates the presence of these functional groups.
- **Baeyer-Villiger Oxidation**: This reaction is characteristic of ketones, particularly aliphatic ketones. It involves the oxidation of ketones to esters.

### Step 2: Analyze the Given Information
The problem states that the organic compound does not react with Tollen's reagent. This means that the compound cannot be an aldehyde or a terminal alkyne, as both would give a positive result with Tollen's reagent.

### Step 3: Identify Possible Functional Groups
Since the compound does not react with Tollen's reagent, we can eliminate:
- **Aldehydes**: They would give a positive Tollen's test.
- **Terminal Alkynes**: They would also give a positive Tollen's test.

This leaves us with ketones as the possible functional group.

### Step 4: Confirm the Baeyer-Villiger Oxidation
The problem states that the compound undergoes Baeyer-Villiger oxidation, which is typical for aliphatic ketones. Therefore, the compound must be an aliphatic ketone.

### Step 5: Conclusion
Based on the analysis, the organic compound that does not react with Tollen's reagent but undergoes Baeyer-Villiger oxidation is an aliphatic ketone.

### Final Answer
The compound is an aliphatic ketone.

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