Home
Class 12
CHEMISTRY
Consider the reaction RCHO + NH(2)NH(2...

Consider the reaction
`RCHO + NH_(2)NH_(2) rarr R - CH = N NH_(2)`
What sort of reaction is it?

A

Electrophilic addition - elimination reaction

B

Free radical addition - elimination reaction

C

Electrophilic substitution - elimination reaction

D

Nucleophilic addition - elimination reaction

Text Solution

AI Generated Solution

The correct Answer is:
To determine the type of reaction occurring in the given equation: **Reaction:** \[ RCHO + NH_2NH_2 \rightarrow R-CH=N-NH_2 \] ### Step-by-Step Solution: 1. **Identify the Reactants:** - The reactants in the reaction are an aldehyde (RCHO) and hydrazine (NH2NH2). - Aldehydes contain a carbonyl group (C=O) and are known for their reactivity with nucleophiles. 2. **Nucleophilic Addition:** - The nitrogen atom in hydrazine (NH2) acts as a nucleophile and attacks the electrophilic carbon atom of the carbonyl group (C=O) in the aldehyde. - This results in the formation of a tetrahedral intermediate where the carbonyl oxygen becomes an alcohol (–OH) and the nitrogen from hydrazine is added to the carbon. 3. **Formation of the Intermediate:** - The intermediate formed after the nucleophilic addition can be represented as: \[ R-CH(OH)-N(NH_2) \] - Here, the carbon is bonded to an –OH group and the hydrazine moiety. 4. **Elimination of Water:** - The next step involves the elimination of a water molecule (H2O) from the intermediate. - This occurs as the hydroxyl group (–OH) and a hydrogen atom from the nitrogen (NH2) are removed, leading to the formation of a double bond between carbon and nitrogen. 5. **Final Product Formation:** - After the elimination of water, the final product is a hydrazone: \[ R-CH=N-NH_2 \] - This structure features a carbon-nitrogen double bond and is characteristic of hydrazones. 6. **Conclusion:** - The overall reaction involves two main steps: nucleophilic addition followed by elimination (specifically, the elimination of water). - Therefore, the type of reaction can be classified as a **nucleophilic addition-elimination reaction**. ### Final Answer: The reaction is a **nucleophilic addition followed by elimination**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Assertion (A) : In the reaction, N_(2)+3H_(2) rarr 2NH_(3) , the rate of reaction is different in terms of N_(2), H_(2) and NH_(3) . Reason (R ): The rate of reaction is equal to the rate of disappearance of a reactant or rate of formation of a Product.

Conisder the chemical reaction N_(2)(g) + 3H_(2)(g) rarr 2NH_(3)(g) The rate of this reaction can be expressed in terms of time derivatives of the concentration of N_(2)(g), H_(2)(g) , or NH_(3)(g) . Identify the correct relationship among the rate expresisons.

Balance the following reactions: NH_(3)+O_(2) rarr NO + H_(2)O

First product of the reaction between RCHO and NH_(2) NH_(2) :-

Complete the given redox reaction CuO+NH_(3) rarr

How many grams of urea on heating yield 10^(22) molecules of biuret by the reaction : 2CO(NH_(2))_(2) rarr H_(2)N - CO - NH - CO - NH_(2) + NH_(3) ?

For the reaction N_(2)(g) + 3H_(2)(g) rarr 2NH_(2)(g) Which of the following is correct?

Equivalent mass of the reaction C_(6)H_(5)NO_(2)rarr C_(6)H_(5)NH_(2) .

Complete the given redox reaction: KMnO_(4)+NH_(3) rarr