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A : 2-methyl propanal can give Cannizzar...

A : 2-methyl propanal can give Cannizzaro reaction as well as aldol condensation.
R : It has `alpha`-hydrogen atom.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is false statement but Reason is true, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason provided: **Assertion (A):** 2-methylpropanal can give Cannizzaro reaction as well as aldol condensation. **Reason (R):** It has alpha-hydrogen atom. ### Step 1: Understanding the Cannizzaro Reaction The Cannizzaro reaction occurs with aldehydes that do not have alpha-hydrogen atoms. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. ### Step 2: Identifying the Structure of 2-Methylpropanal 2-Methylpropanal (also known as isobutyraldehyde) has the following structure: - CH3-CH(CH3)-CH2-CHO In this structure, we can identify the alpha-carbon (the carbon adjacent to the carbonyl group) and the alpha-hydrogens. ### Step 3: Checking for Alpha-Hydrogens In 2-methylpropanal: - The alpha-carbon is the carbon attached to the carbonyl (CHO). - The alpha-hydrogens are the hydrogens attached to the alpha-carbon. Since 2-methylpropanal has an alpha-carbon with attached hydrogens, it has alpha-hydrogens. ### Step 4: Aldol Condensation Aldol condensation occurs when aldehydes (or ketones) with alpha-hydrogens undergo a reaction in which they form a β-hydroxy aldehyde (or ketone) upon reaction with themselves or another carbonyl compound. Since 2-methylpropanal has alpha-hydrogens, it can undergo aldol condensation. ### Step 5: Conclusion - **Assertion (A)** is false because 2-methylpropanal cannot undergo the Cannizzaro reaction (it has alpha-hydrogens). - **Reason (R)** is true because 2-methylpropanal does have alpha-hydrogens. Thus, the correct answer is that the assertion is false, and the reason is true. ### Final Answer The assertion is false, and the reason is true. Therefore, the correct option is that the assertion is false while the reason is true. ---
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