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A : Formaldehyde undergoes Cannizzaro re...

A : Formaldehyde undergoes Cannizzaro reaction in the presence of `H^(+)`.
R : Formaldehyde has two `alpha`-Hydrogen atoms.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we need to analyze both statements carefully. ### Step 1: Understand the Assertion The assertion states: "Formaldehyde undergoes Cannizzaro reaction in the presence of H+." - The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. In this reaction, one molecule of aldehyde is oxidized to a carboxylic acid while another molecule is reduced to an alcohol. - Formaldehyde (HCHO) is the simplest aldehyde and does not have any alpha-hydrogens, as it has no carbon atoms adjacent to the carbonyl group (C=O). **Conclusion for Assertion**: The assertion is true because formaldehyde does undergo Cannizzaro reaction in the presence of H+. ### Step 2: Understand the Reason The reason states: "Formaldehyde has two alpha-hydrogen atoms." - Alpha-hydrogens are the hydrogen atoms attached to the carbon atom adjacent to the carbonyl carbon. - In the case of formaldehyde (HCHO), there are no alpha-hydrogens because there is only one carbon atom, and thus no adjacent carbon to provide alpha-hydrogens. **Conclusion for Reason**: The reason is false because formaldehyde does not have any alpha-hydrogens. ### Final Conclusion - The assertion is true, and the reason is false. Therefore, the correct answer to the question is that the assertion is true, and the reason is false. ### Summary of the Answer: - Assertion (A): True - Reason (R): False
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Formaldehyde gives Cannizzaro's reaction while acetaldehyde does not. Why ?

Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction. Reason : Those aldehydes which have alpha -H atom undergo Cannizzaro reaction.