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What is Z in the following sequence of r...

What is Z in the following sequence of reactions?
`Z overset(PCl_(3))toX overset(alc.KOH)to Y underset((ii)H_(2)O boil)overset((i)Conc.H_(2)SO_(4))toZ`

A

`CH_(3)CH_(2)CH_(2)OH`

B

`CH_(3)CHOHCH_(3)`

C

`(CH_(3)CH_(2))_(2)CHOH`

D

`CH_(3)-CH=CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine what Z is in the given sequence of reactions, we will analyze each step of the reaction sequence carefully. ### Step-by-Step Solution: 1. **Identify the starting compound (Z)**: Let's denote the starting compound as Z. The question provides a sequence of reactions, and we need to identify what Z is. 2. **Reaction with PCl₃**: The first reaction involves Z reacting with phosphorus trichloride (PCl₃). PCl₃ typically converts alcohols to alkyl chlorides. Therefore, Z must be an alcohol. 3. **Formation of X**: When Z reacts with PCl₃, it forms X, which is an alkyl chloride. The general reaction can be represented as: \[ Z + PCl₃ \rightarrow X \] Here, the hydroxyl group (-OH) in Z is replaced by a chlorine atom (-Cl) in X. 4. **Reaction with alcoholic KOH**: The next step involves X reacting with alcoholic KOH. Alcoholic KOH is a strong base and is used for elimination reactions. In this case, X will undergo elimination to form an alkene (Y). The reaction can be represented as: \[ X \overset{alc.KOH}{\rightarrow} Y \] This suggests that X must be a secondary or tertiary alkyl chloride to facilitate elimination. 5. **Formation of Y**: The product Y is an alkene formed from the elimination of HCl from X. 6. **Reaction with concentrated H₂SO₄**: The next step involves Y reacting with concentrated sulfuric acid (H₂SO₄). This reaction typically leads to the formation of an alkyl hydrogen sulfate, which can then be hydrolyzed to regenerate the alcohol. The reaction can be represented as: \[ Y \overset{conc.H₂SO₄}{\rightarrow} Z' \] Here, Z' is a compound that can be hydrolyzed. 7. **Hydrolysis with water**: Finally, Z' undergoes hydrolysis when treated with water (boiling), leading to the regeneration of Z: \[ Z' + H₂O \rightarrow Z \] This indicates that Z is the same as the original alcohol we started with. ### Conclusion: Based on the sequence of reactions and the transformations involved, we can conclude that Z is an alcohol that can be converted to an alkyl chloride, then to an alkene, and finally back to the original alcohol through hydrolysis. ### Final Answer: Z is an alcohol that can undergo the described reactions.
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Exercise
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  4. Which of the following is the strongest base ?

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  9. When wine is exposed to air it becomes sour due to

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  10. Starch is converted to maltose by

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  11. Rectified spirit is a mixture of

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  12. Methanol and ethanol can be distinguished by

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  13. In Reimer Tiemann reaction dichlorocarbene acts as

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  14. Carbolic acid is

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  15. Which of the following is a trihydric phenol ?

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  16. Which of the following is the strongest acid ?

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  17. Electrophilic subsitution reaction in phenol take place at :

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  18. The following reaction is known as : Phenol overset(1.CHCl(3)//NaO...

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