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The heating of phenyl-methyl ethers with...

The heating of phenyl-methyl ethers with `HI` produces

A

Ethyl chlorides

B

lodoenzene

C

Phenol

D

Benzene

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The correct Answer is:
D
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The heating of benzyl methyl ether with HI produces majorly

(a) Explain why cleavage of phenyl ethers with HBr always produces phenol and alkyl bromides and not bromobenzene and alkanols. (b) Give reasons for the following: (i) The dipole moment of diethyl ether (1.18D) is lower than that of water (1.84D). (ii) The C-O-C bond angle in ethers is higher than H-O-H angle in water though oxygen is sp3 hybridized in both the cases. (iii) Dimethyl ether is completely miscible with water but diethyl ether is soluble in water to a small extent.

The ether when treated with HI produces

The ether when treated with HI produces:

Account for the product formed when phenyl ethyl ether reacts with HI.

1-methyl-1-phenyl ethylene oxide when treated with HBr produce

Phenyl methyl ether reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol. Why?

The products obtained when benzyl phenyl ether is heated with HI in the mole ratio 1 : 1 are 1. Phenol 2. Benzyl alcohol 3. Benzyl iodide 4. lodobenzene

What happens when diethyl ether is heated with HI at 373 K ?

Reaction of which among the following ethers with HI in cold leads to the formation of methyl alcohol ?

AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section - C (Previous Years questions)
  1. Which one is the most acidic compound?

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  2. The heating of phenyl-methyl ethers with HI produces

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  3. The reaction can be classified as

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  4. Which of the following reagents would distinguish ciscyclopenta -1,2-d...

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  5. Reaction of phenol with chloroform in presence of dilute sodium hydrox...

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  6. Which of the following is not the product of dehydration of

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  7. Which of the following reaction(s) can be used for the preparation of ...

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  8. The reaction CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|...

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  9. Among the following sets of reactants which one produces anisole?

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  10. Identify Z in the sequence of reactions : CH(3)CH(2)CH=CH(2)underse...

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  11. Among the following ethers, which one will produce methyl alcohol on t...

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  12. In the following reaction The major product is

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  13. In the following reactions . ltb rgt CH3-overset(CH3)overset(|)CH-unde...

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  14. Which one of the following compounds has the most acidic nature ?

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  15. Which one of the following is most reactive towards electrophillic rea...

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  16. Among the following four compounds (a) Phenol (b) methyl phenol ...

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  17. When glycerol is treated with excess of HI, it produces -

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  18. Which one of the following compounds will be most readily dehydrated?

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  19. Which of the following conformers for ethylene glycol is most stable ?

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  20. Consider the following reaction "Ethanol" overset(PBr(3))to X overset...

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