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A : When C(2) H(5) - O- CH(3) is reacte...

A : When `C_(2) H_(5) - O- CH_(3)` is reacted with one mole of Hl then `C_(2)H_(5)OH` & `CH_(3) I` is formed .
R : It is `S_(N)1` reaction

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question step by step, let's analyze the assertion and reason provided: ### Step 1: Analyze the Assertion The assertion states that when \( C_2H_5OCH_3 \) (ethyl methyl ether) is reacted with one mole of HI (hydroiodic acid), the products formed are \( C_2H_5OH \) (ethanol) and \( CH_3I \) (methyl iodide). 1. **Reaction Mechanism**: - The ether \( C_2H_5OCH_3 \) reacts with HI. The oxygen in the ether has lone pairs that can protonate by the hydrogen ion (H⁺) from HI. - This leads to the formation of a protonated ether, which is more reactive. 2. **Cleavage of Ether**: - The protonated ether will undergo cleavage, leading to the formation of \( C_2H_5OH \) and \( CH_3I \). - The reaction can be summarized as: \[ C_2H_5OCH_3 + HI \rightarrow C_2H_5OH + CH_3I \] Thus, the assertion is **true**. ### Step 2: Analyze the Reason The reason states that the reaction is an \( S_N1 \) reaction. 1. **Understanding \( S_N1 \) Mechanism**: - An \( S_N1 \) reaction involves the formation of a carbocation intermediate. It typically occurs with tertiary or some secondary substrates where the carbocation is stable. - In this case, the ether does not form a stable carbocation; instead, it undergoes a bimolecular nucleophilic substitution. 2. **Actual Mechanism**: - The reaction proceeds via an \( S_N2 \) mechanism, where the nucleophile (I⁻) attacks the less hindered carbon atom directly, leading to the formation of products in a single step without forming a stable carbocation. Thus, the reason is **false**. ### Conclusion - The assertion is true, and the reason is false. Therefore, the correct option is: **Assertion True, Reason False** (Option 3).
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  2. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  3. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  4. A : In esterification reaction , HCOOH is the most reactive acid among...

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  5. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  6. Phenol is less acidic than........... .

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  7. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  8. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  9. A : Grignard's reagent is prepared in the presence of ether . R :...

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  10. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  11. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  12. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  13. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  14. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  20. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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