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A : CH(3)-underset(CH(3))underset(|)ov...

A : `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-O-CH_(3)` on reaction with conc. Hl gives ` CH_(3) - underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-I and CH_(3)OH` major product .
R : This reaction proceed by `S_(N)1` mechanism .

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2)

C

If Assertion is true statement but Reason is false , then mark (3)

D

If both Assertion and Reason are false statements , then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the assertion and reason provided, and verify their correctness step by step. ### Step 1: Analyze the Assertion The assertion states that the compound `CH3-C(CH3)2-O-CH3` reacts with concentrated HI to give `CH3-C(CH3)2-I` and `CH3OH` as major products. 1. **Identify the Reactant**: The reactant is an ether, specifically a methoxy derivative of a tert-butyl structure. 2. **Reaction with HI**: When this ether reacts with concentrated HI, the ether bond (C-O) is cleaved. The oxygen atom in the ether can be protonated by HI, making it a better leaving group. 3. **Formation of Products**: The cleavage of the ether bond leads to the formation of a tertiary carbocation and methanol (CH3OH). The iodide ion (I-) from HI can then attack the carbocation to form the iodo compound. **Conclusion for Assertion**: The assertion is true as the reaction does produce the stated major products. ### Step 2: Analyze the Reason The reason states that the reaction proceeds by an SN1 mechanism. 1. **Understanding SN1 Mechanism**: The SN1 mechanism involves two steps: - Formation of a carbocation (rate-determining step). - Nucleophilic attack by the iodide ion on the carbocation. 2. **Stability of Carbocation**: In this case, the formation of a tertiary carbocation is favored due to its stability, which supports the SN1 pathway. 3. **Product Formation**: The nucleophile (I-) attacks the carbocation leading to the formation of the iodo compound. **Conclusion for Reason**: The reason is also true, as it correctly describes the mechanism of the reaction. ### Final Conclusion Both the assertion and the reason are true, and the reason correctly explains the assertion. Therefore, the correct option is: **Option 1**: Both assertion and reason are true, and reason is the correct explanation of the assertion.
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AAKASH INSTITUTE ENGLISH- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  2. A : When C(2) H(5) - O- CH(3) is reacted with one mole of Hl then C(2...

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  3. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  4. A : In esterification reaction , HCOOH is the most reactive acid among...

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  5. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  6. Phenol is less acidic than........... .

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  7. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  8. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  9. A : Grignard's reagent is prepared in the presence of ether . R :...

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  10. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  11. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  12. A : bond angle in ether is slightly greater than normal tetrahedral an...

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  13. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  14. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : The reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for ...

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  20. A : The dehydration of ethyl alcohol in presence of Al(2)O(3) at 633 ...

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