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Which of the following is not possible d...

Which of the following is not possible directly in nitrobenzene?

A

Halogenation

B

Sulphonation

C

Nitration

D

Alkylation

Text Solution

AI Generated Solution

To solve the question "Which of the following is not possible directly in nitrobenzene?", we need to analyze the effects of the nitro group (-NO2) on the reactivity of the benzene ring. Here’s a step-by-step solution: ### Step 1: Understand the Nature of the Nitro Group The nitro group (-NO2) is a strong electron-withdrawing group. It pulls electron density away from the benzene ring through resonance and inductive effects. This significantly affects the reactivity of the benzene ring towards electrophilic substitution reactions. **Hint:** Remember that electron-withdrawing groups decrease electron density on the aromatic ring, making it less reactive towards electrophiles. ### Step 2: Identify the Positions of Electrophilic Attack ...
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Knowledge Check

  • Which of the following reaction is possible ?

    A
    `C_(6)H_(5)OH+HBr to C_(6)H_(5)Br+H_(2)O`
    B
    `(CH_(3))_(3)C Cl+NaOCH_(3) to (CH_(3))_(3)COCH_(3)+NaCl`
    C
    D
  • Which of the following reaction is possible ?

    A
    `C_(6)H_(5)OH+HBrtoC_(6)H_(5)Br+H_(2)O`
    B
    `(CH_(3))_(3)C Cl+NaOCH_(3)to(CH_(3))_(3)COCH_(3)+NaCl`
    C
    D
  • Which of the following give aniline by reduction of nitrobenzene?

    A
    `H_(2) // Pd- C`
    B
    `Sn + HCl`
    C
    `Fe+ HCl`
    D
    `LiAlH_(4)`
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