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Isopropylamine overset(KMnO(4))rarr X ov...

Isopropylamine `overset(KMnO_(4))rarr X overset(H_(3)^(+)O)rarr Y`
In the above sequence X and Y are

A

Acetaldehyde, Ethanal

B

Ethanal, Ketimine

C

Ketimine, Acetone

D

Acelone, Propan-2-ol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the products X and Y formed from the reaction of isopropylamine with potassium permanganate (KMnO4) followed by treatment with hydronium ion (H3O+). ### Step-by-Step Solution: 1. **Identify the Structure of Isopropylamine**: - Isopropylamine has the chemical structure: \[ \text{CH}_3\text{CH}(\text{NH}_2)\text{CH}_3 \] - This can also be represented as: \[ \text{(CH}_3)_2\text{CHNH}_2 \] 2. **Oxidation with KMnO4**: - When isopropylamine is treated with KMnO4, it undergoes oxidation. In this process, hydrogen atoms are removed from the nitrogen and the adjacent carbon atoms. - The oxidation will convert the amine group into an imine group, resulting in the formation of a compound known as ketamine. - The structure of the product (X) after oxidation can be represented as: \[ \text{CH}_3\text{C}(\text{CH}_3)=\text{NH} \] - This compound is called **ketamine**. 3. **Hydrolysis with H3O+**: - The next step involves treating the ketamine with hydronium ions (H3O+), which leads to hydrolysis. - During hydrolysis, the double bond between the carbon and nitrogen is broken, and a carbonyl group (C=O) is formed. - The hydrolysis of ketamine results in the formation of acetone (Y) and ammonia (NH3) as a byproduct. - The structure of the product (Y) is: \[ \text{CH}_3\text{C}(\text{O})\text{CH}_3 \] - This compound is known as **acetone**. 4. **Final Products**: - Therefore, the final products of the reaction sequence are: - **X = Ketamine** - **Y = Acetone** ### Summary of the Solution: - X is **Ketamine** (formed from isopropylamine by oxidation with KMnO4). - Y is **Acetone** (formed from ketamine by hydrolysis with H3O+).
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