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The order of strength of hydrogen bonds ...

The order of strength of hydrogen bonds is

A

`H_2N-HcdotsNH_3gtHO-HcdotsOH_2gtF-HcdotsF-H`

B

`H_2N-HcdotsNH_3ltHO-HcdotsOH_2ltF-HcdotsF-H`

C

`H_2N-HcdotsNH_3gtF-HcdotsF-HgtHO-HcdotsOH_2`

D

`H_2N-HcdotsNH_3ltHO-HcdotsOH_2gtF-HcdotsF-H`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of strength of hydrogen bonds, we need to consider the electronegativity of the elements involved. Hydrogen bonds occur when hydrogen is covalently bonded to a highly electronegative atom, which creates a partial positive charge on hydrogen and a partial negative charge on the electronegative atom. The strength of hydrogen bonds increases with the electronegativity of the atom bonded to hydrogen. ### Step-by-Step Solution: 1. **Identify the Elements Involved**: The elements typically involved in hydrogen bonding are nitrogen (N), oxygen (O), and fluorine (F). 2. **Understand Electronegativity**: Electronegativity is a measure of an atom's ability to attract and hold onto electrons. The higher the electronegativity, the stronger the hydrogen bond formed with hydrogen. 3. **Compare Electronegativity Values**: - Fluorine (F) has the highest electronegativity value (approximately 4.0). - Oxygen (O) has a lower electronegativity value (approximately 3.5). - Nitrogen (N) has the lowest electronegativity value among these three (approximately 3.0). 4. **Determine the Order of Strength**: - Since fluorine is the most electronegative, the hydrogen bond formed with fluorine (as in HF) will be the strongest. - The hydrogen bond formed with oxygen (as in H2O) will be the next strongest. - The hydrogen bond formed with nitrogen (as in NH3) will be the weakest. 5. **Final Order of Strength**: - The order of strength of hydrogen bonds is: 1. Fluorine (HF) 2. Oxygen (H2O) 3. Nitrogen (NH3) ### Conclusion: The correct order of strength of hydrogen bonds is: **Fluorine > Oxygen > Nitrogen**.
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Knowledge Check

  • Hydrogen bonds are formed in many compounds e.g. H_(2)O , HF, NH_(3) . The boiling point of such compounds depends to a extent on the strength of hydrogen bond and the number of hydrogen bonds. The correct decreasing order of the boiling points above compounds is

    A
    `HF gt H_(2) O gt NH_(3)`
    B
    `H_(2) O gt HF gt NH_(3)`
    C
    `NH_(3) gt HF gt H_(2)O`
    D
    `NH_(3) gt H_(2)O gt HF`
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