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If a non-volatile solute is dissolved in...

If a non-volatile solute is dissolved in a volatile solvent relative lowering of vapour pressure is equal to

A

Moles of solute

B

Moles of solvent

C

Mole fraction of solute

D

Mole fraction of solvent

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The correct Answer is:
To solve the question regarding the relative lowering of vapor pressure when a non-volatile solute is dissolved in a volatile solvent, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Concept**: - When a non-volatile solute is added to a volatile solvent, the vapor pressure of the solvent decreases. This phenomenon is known as the relative lowering of vapor pressure. 2. **Defining Vapor Pressure**: - Let \( P_0 \) be the vapor pressure of the pure solvent. - Let \( P_t \) be the vapor pressure of the solution after the solute has been added. 3. **Using Raoult's Law**: - According to Raoult's Law, the relative lowering of vapor pressure can be expressed as: \[ \text{Relative lowering of vapor pressure} = \frac{P_0 - P_t}{P_0} \] - This can also be written as: \[ \frac{P_0 - P_t}{P_0} = \frac{n_{solute}}{n_{solute} + n_{solvent}} \] - Here, \( n_{solute} \) is the number of moles of the solute and \( n_{solvent} \) is the number of moles of the solvent. 4. **Mole Fraction**: - The mole fraction of the solute (\( X_{solute} \)) can be defined as: \[ X_{solute} = \frac{n_{solute}}{n_{solute} + n_{solvent}} \] - Therefore, the relative lowering of vapor pressure can also be expressed as: \[ \text{Relative lowering of vapor pressure} = X_{solute} \] 5. **Conclusion**: - From the above derivation, we conclude that the relative lowering of vapor pressure is equal to the mole fraction of the solute. ### Final Answer: The relative lowering of vapor pressure is equal to the **mole fraction of the solute**.
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