Home
Class 12
CHEMISTRY
Consider the following statements (I) ...

Consider the following statements
(I) `Zr^(4+)` and `Hf^(4+)` have almost same ionic radii
(II) Lanthanoids liberate `H_2` when treated with dilute acids.
(III) The ionic radii of trivalent lanthanoids steadily increase with increase in atomic number.
The correct statement(s) is/ are

A

I ,II

B

I , III

C

Only II

D

I, II, III

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze each of the three statements provided regarding Zr^(4+), Hf^(4+), lanthanoids, and their properties. ### Step 1: Analyze Statement I **Statement I:** Zr^(4+) and Hf^(4+) have almost the same ionic radii. - **Explanation:** Zirconium (Zr) and Hafnium (Hf) are both in Group 4 of the periodic table. Zr is in the 4th period, while Hf is in the 5th period. Due to the lanthanoid contraction, the ionic radii of Zr^(4+) and Hf^(4+) are indeed very similar. Therefore, this statement is **correct**. ### Step 2: Analyze Statement II **Statement II:** Lanthanoids liberate H2 when treated with dilute acids. - **Explanation:** Lanthanoids (the 14 elements from Cerium to Lutetium) react with dilute acids to liberate hydrogen gas (H2). This is a well-known property of these metals. Therefore, this statement is also **correct**. ### Step 3: Analyze Statement III **Statement III:** The ionic radii of trivalent lanthanoids steadily increase with an increase in atomic number. - **Explanation:** This statement is **incorrect**. The ionic radii of trivalent lanthanoids actually decrease with an increase in atomic number due to the lanthanoid contraction. As the atomic number increases, electrons are added to the 4f subshell, which has poor shielding effects, leading to a stronger effective nuclear charge and thus a decrease in ionic size. ### Conclusion Based on the analysis: - Statement I is correct. - Statement II is correct. - Statement III is incorrect. Thus, the correct statements are I and II. ### Final Answer The correct statements are I and II.
Promotional Banner

Topper's Solved these Questions

  • HYDROGEN

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (SECTION - D) (Assertion-Reason Type question)|15 Videos
  • MOCK TEST 1

    AAKASH INSTITUTE ENGLISH|Exercise EXAMPLE|28 Videos

Similar Questions

Explore conceptually related problems

Consider the following statements : (I) The radius of an anion is larger than that of the parent atom (II) The ionization energy generally increases with increasing atomic number in a period. (III) The electronegativity of an element is the tendency of an isolated atom to at tract an electron. Which of the above statements is/are correct?

Consider the following statements : (I) The radius of an anion is larger than that of the parent atom (II) The ionization energy generally increases with increasing atomic number in a period. (III) The electronegativity of an element is the tendency of an isolated atom to at tract an electron. Which of the above statements is/are correct?

Consider the following statement: (I) The radius of an anion is larger than that of the parent atom. (II) the ionization energy generally increases with increasing atomic number in a period. (III) The electronegativity of an element is the tendency of an isolated atom to attract an electron. Which of the above statement is/are correct?

Consider the following statements: (I) La (OH)_(3) is the least basic among the hydroxides of Ianthanoids. (II) Zr^(4+) and Hf^(4+) possess almost same ionic radii. (III) Cr^(4+) can act as an oxidising agent . which of the above statement is/ are true?

Consider the following statements : The mean free path of gas molecules I. decreases with increase in concentration II. increases with decrease in pressure at constant temperature III. decreases with increase in molecular size Which of the above statements are correct?

Assign reason for each of the following statement: (i) The largest number of oxidation states are exhibited by the elements in their row transition elements. (ii) The atomic radii decrease in Size with the increasing atomic number in the lanthanoid series

The following are some statements related to II group metals I. The reaction with water increases from Be to Ba II. The ionic nature of hydrides decreases from Be to Ba III. The thermal stability of the peroxides increases with increase in cationic size IV. The solubility of sulphates increases from Mg to Ba The correct options are :

Consider the following statement in respect of Lantinanoids : (i) The basic strength of hydroxides of lanthanoids increases from La (OH)_(3) to Lu (OH)_(3) . (ii) The lanthanoid ions Lu^(3+), Yb^(2+) and Ce^(4+) are diamagnetic. Which of the statements (s) given above is /are correct ?

Consider the following statements conerning food chains (i) Removal of 80% tigers from an area resulted in greatly increased growth of vegetation (ii) Removal of most of the carnivores resulted in an increased population of deers (iii) The length of food chains is generally limited to 3 - 4 trophic levels due to energy loss (iv) The length of food chains may vary from 2 to 8 trophic levels Which two of the above statements are correct?

Consider the following statements conerning food chains (i) Removal of 80% tigers from an area resulted in greatly increased growth of vegetation (ii) Removal of most of the carnivores resulted in an increased population of deers (iii) The length of food chains is generally limited to 3 - 4 trophic levels due to energy loss (iv) The length of food chains may vary from 2 to 8 trophic levels Which two of the above statements are correct?

AAKASH INSTITUTE ENGLISH-M0ck test 26-EXAMPLE
  1. The electronic configuration of one of the coinage metals is

    Text Solution

    |

  2. In which compound does vanadium has an oxidation number of +4 ?

    Text Solution

    |

  3. Transition metals and their compounds show catalytic properties becaus...

    Text Solution

    |

  4. The common transition metals in brass and bronze is

    Text Solution

    |

  5. Which group elements of first transition series has the highest parama...

    Text Solution

    |

  6. The product formed by the fusion of MnO2 with KHO in the presence of a...

    Text Solution

    |

  7. The number of equivalent Cr-O bonds in CrO4^(2-) is

    Text Solution

    |

  8. Why actinoid contraction is more than lanthanoid contraction

    Text Solution

    |

  9. CrO3 dissolves in aqueous NaOh to give

    Text Solution

    |

  10. Which of the following can be oxidised by acidified K2Cr2O7 ?

    Text Solution

    |

  11. The most common oxidation state exhibited by lanthanoids and actinoids...

    Text Solution

    |

  12. The paramagnetic lanthanoid ion among the following is

    Text Solution

    |

  13. The nature of CrO and Cr2O3 is respectively

    Text Solution

    |

  14. Identify the incorrect statement with respect to KMnO4

    Text Solution

    |

  15. Consider the following statements (I) Zr^(4+) and Hf^(4+) have almos...

    Text Solution

    |

  16. The reddish brown gas produced by heating KCl with solid K2Cr2O7 and...

    Text Solution

    |

  17. Chromate ion, CrO4^(2-) is

    Text Solution

    |

  18. When KMnO4 reacts with I^- in a slightly alkaline and acidic medium, t...

    Text Solution

    |

  19. Which of the following characteristic is not the point of similarity b...

    Text Solution

    |

  20. When a chromite ore (A) is fused with sodium carbonate in free excess ...

    Text Solution

    |