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F3C-CH=CH2 overset(HBr)(rarr) (A) overse...

`F_3C-CH=CH_2 overset(HBr)(rarr) (A) overset(Nal) underset(dry . "acetone")(rarr) (B) `

A

`F_3C-CH(Br)-CH_3 and F_3C-CH(I)-CH_3`

B

`F_3C-CH_2-CH_2Br and F_3C-CH_2-CH_2 I`

C

`BrF_2C-CH=CH_2 and IF_2C-CH=CH_2`

D

`BrF_2C-CH_2-CH_2Br and IF_2C-CH_2-CH_2I`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question step by step, we will analyze the reactions of the compound \( F_3C-CH=CH_2 \) with \( HBr \) and then with \( NaI \) in dry acetone. ### Step 1: Reaction of \( F_3C-CH=CH_2 \) with \( HBr \) 1. **Identify the Reactants**: We have an alkene \( F_3C-CH=CH_2 \) and \( HBr \). 2. **Markovnikov's Rule**: According to Markovnikov's rule, when \( HBr \) adds to the alkene, the hydrogen atom (H) will attach to the carbon with more hydrogen atoms (the less substituted carbon), and the bromine (Br) will attach to the carbon with fewer hydrogen atoms (the more substituted carbon). 3. **Addition of HBr**: - The double bond between \( CH \) and \( CH_2 \) will break. - The hydrogen from \( HBr \) will add to the \( CH_2 \) carbon, and the bromine will add to the \( CH \) carbon. 4. **Product A**: The resulting product after this addition is: \[ A = F_3C-CH(Br)-CH_3 \] ### Step 2: Reaction of Product A with \( NaI \) in Dry Acetone 1. **Identify the Reactants**: The product \( A \) is \( F_3C-CH(Br)-CH_3 \) and it reacts with \( NaI \) in dry acetone. 2. **Finkelstein Reaction**: This is a nucleophilic substitution reaction where iodide ion (\( I^- \)) from \( NaI \) will replace the bromine atom. 3. **Better Leaving Group**: Bromine is a better leaving group than fluorine, so the iodide ion will replace the bromine atom. 4. **Product B**: The resulting product after this substitution is: \[ B = F_3C-CH(I)-CH_3 \] ### Final Products - **Product A**: \( F_3C-CH(Br)-CH_3 \) - **Product B**: \( F_3C-CH(I)-CH_3 \) ### Conclusion After analyzing the reactions, we can conclude that: - The correct answer for product A is \( F_3C-CH(Br)-CH_3 \). - The correct answer for product B is \( F_3C-CH(I)-CH_3 \).
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AAKASH INSTITUTE ENGLISH-Mock test 27-EXAMPLE
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  2. Which of the following complexes is an inner orbtial complex ?

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  3. Which of the following pairs does not exhibit colour in solution ?

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  4. Which of the following complexes will show jahn-Teller distortion?

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  5. compounds having similar geometry have different magnetic moment(T/F)

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  6. The homoleptic complex is

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  7. Which of the following is not a metal carbonyl?

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  8. In which of the following carbonyls, the bond length of CO is the high...

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  9. The terminal and bridged CO ligands in the compound [Co(2) (CO)(8)] ar...

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  10. The addition of four amine groups to a metal ion (X^(2+)) shows a stab...

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  11. Excess of copper and iron are removed mainly by which of the following...

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  12. Ethylidene chloride is a/an…..

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  13. IUPAC nomenclature of

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  14. Major product of the given reaction is

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  15. Which of the following will not lead to the formation of an alkyl hali...

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  16. F3C-CH=CH2 overset(HBr)(rarr) (A) overset(Nal) underset(dry . "acetone...

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  17. For the reaction C(2)H(5) OH + HX to C2 H(5) X + H(2)O , the order of ...

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  18. CH3-C-= CH + Br2 overset (CCl4)(rarr)(A) The product (A) is

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  19. Among the following halide ions (X^-) reaction, which is feasible is?

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