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In anthrcene ,number of pi electrons is ...

In anthrcene ,number of pi electrons is equal to x. the value of x is

A

6

B

10

C

14

D

12

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The correct Answer is:
To determine the number of pi electrons in anthracene, we can follow these steps: ### Step 1: Understand the Structure of Anthracene Anthracene is a polycyclic aromatic hydrocarbon composed of three fused benzene rings in a linear arrangement. It has a total of 14 carbon atoms and 10 hydrogen atoms. **Hint:** Remember that anthracene consists of multiple fused benzene rings. ### Step 2: Identify the Hybridization of Carbon Atoms In anthracene, each carbon atom is sp² hybridized. This hybridization allows for the formation of one sigma bond with adjacent carbon atoms and one pi bond with the adjacent carbon atom. **Hint:** Recall that sp² hybridization leads to the formation of one pi bond per carbon atom. ### Step 3: Count the Number of Pi Bonds In anthracene, there are 7 pi bonds formed between the carbon atoms. This can be visualized by drawing the structure or recognizing that each benzene ring contributes to the overall pi bonding. **Hint:** Count the number of double bonds in the structure of anthracene to determine the number of pi bonds. ### Step 4: Calculate the Total Number of Pi Electrons Since each pi bond consists of 2 electrons, the total number of pi electrons can be calculated as follows: \[ \text{Total Pi Electrons} = \text{Number of Pi Bonds} \times 2 \] \[ \text{Total Pi Electrons} = 7 \times 2 = 14 \] **Hint:** Remember that each pi bond contributes 2 electrons to the total count. ### Step 5: Verify with Huckel's Rule According to Huckel's rule, for a compound to be aromatic, it must have \(4n + 2\) pi electrons, where \(n\) is a non-negative integer. For \(n = 3\): \[ 4(3) + 2 = 12 + 2 = 14 \] This confirms that anthracene is aromatic and has 14 pi electrons. **Hint:** Use Huckel's rule to confirm the aromaticity and the count of pi electrons. ### Conclusion The value of \(x\), which represents the number of pi electrons in anthracene, is 14. **Final Answer:** \(x = 14\)
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AAKASH INSTITUTE ENGLISH-MOCK TEST 33-Example
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