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1-Bromopentane is more reactive towards...

1-Bromopentane is more reactive towards

A

`S_N2` and `S_N1`

B

`S_N1` and `S_N2`

C

Both `S_N1`

D

Both `S_N2`

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The correct Answer is:
To determine the reactivity of 1-bromopentane towards different nucleophilic substitution mechanisms, we need to analyze its structure and the characteristics of the mechanisms involved. ### Step-by-Step Solution: 1. **Identify the Structure of 1-Bromopentane**: - 1-bromopentane is a straight-chain alkane with a bromine atom attached to the first carbon. Its chemical structure can be represented as CH3-CH2-CH2-CH2-Br. 2. **Determine the Type of Halide**: - The bromine atom is attached to a primary carbon (the first carbon in the chain), making 1-bromopentane a primary alkyl halide. 3. **Understand SN1 and SN2 Mechanisms**: - **SN1 Mechanism**: This is a two-step mechanism where the first step involves the formation of a carbocation. It is favored by tertiary and some secondary alkyl halides due to the stability of the carbocation formed. - **SN2 Mechanism**: This is a one-step mechanism where the nucleophile attacks the carbon atom simultaneously as the leaving group (bromine) departs. It is favored by primary alkyl halides because they do not form stable carbocations. 4. **Analyze the Reactivity of 1-Bromopentane**: - Since 1-bromopentane is a primary halide, it is more likely to undergo the SN2 mechanism rather than SN1. The steric hindrance is low, allowing the nucleophile to attack the carbon atom effectively. 5. **Conclusion**: - Therefore, 1-bromopentane is more reactive towards the SN2 mechanism. ### Final Answer: 1-bromopentane is more reactive towards the SN2 mechanism. ---
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Knowledge Check

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  • AAKASH INSTITUTE ENGLISH-MOCK TEST 34-Example
    1. The correct order of boiling points of alkyl halides is

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    2. For PIC , the rate of reaction is given by the expression CH(3)Br+OH...

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    3. Which of the following alkyl halide will undergo SN 1 reaction is

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    4. The compound which is least reactive among the following in a nucleoph...

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    5. The correct order of reactivity of the following bromides towards SN 1...

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    6. Which of the following statement(s) is/are incorrect regarding SN 1 re...

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    7. Which of the following molecules contain a chiral centre?

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    8. Two enantiomers differ with respect to

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    9. Among the given halides, which will give same product in both SN 1 and...

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    10. The correct statement regarding the transition state of a SN 2 reactio...

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    11. 1-Bromopentane is more reactive towards

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    12. Hybridisation of Acetylene is

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    13. Nucleophilic substitution reaction of optically active halide, PIC is ...

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    14. Shape of PCl5 molecule is

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    15. Number of chlorine atoms which form equatorial bonds in PCl5 molecule ...

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    16. The correcr order of ease of elimination of following groups in the E2...

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    17. Arrange the following compounds in order of ease of dehydrohalogenatio...

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    18. The percentage p-character in sp3 hybridisation is

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    19. Do we call metal carbonyls as organometallics?

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    20. The hybridisation of BeF3- is

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