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The shape of the intermediate formed In ...

The shape of the intermediate formed In nucleophilic addilion reaction of aldehydes and ketones is

A

Trigonal planar

B

Tetrahedral

C

Trigonal bipyramidal

D

Bent

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The correct Answer is:
To determine the shape of the intermediate formed in the nucleophilic addition reaction of aldehydes and ketones, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: - In nucleophilic addition reactions, aldehydes and ketones react with nucleophiles. The general structure of a carbonyl compound (aldehyde or ketone) is R-C(=O)-R', where R and R' can be hydrogen or hydrocarbon groups. 2. **Understand the Carbonyl Group**: - The carbonyl carbon (C=O) is sp² hybridized, which means it has a trigonal planar geometry. However, when a nucleophile attacks, the carbonyl carbon becomes sp³ hybridized. 3. **Nucleophile Attack**: - When the nucleophile (Nu-) attacks the carbonyl carbon, it breaks the π bond between carbon and oxygen, leading to the formation of a new σ bond. This results in the formation of an alkoxide intermediate. 4. **Formation of the Intermediate**: - The structure of the intermediate can be represented as R-C(-Nu)-O⁻. The carbon now has four substituents (two R groups, the nucleophile, and the oxygen atom with a negative charge), which means it is tetrahedral. 5. **Determine the Shape**: - Since the carbon in the intermediate is sp³ hybridized, the geometry around this carbon atom is tetrahedral. 6. **Conclusion**: - Therefore, the shape of the intermediate formed in the nucleophilic addition reaction of aldehydes and ketones is tetrahedral. ### Final Answer: The shape of the intermediate formed in the nucleophilic addition reaction of aldehydes and ketones is **tetrahedral**. ---
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AAKASH INSTITUTE ENGLISH-MOCK TEST 37-Exercise
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  2. The incorrect statement for aldehydes and ketones is

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  3. The shape of the intermediate formed In nucleophilic addilion reaction...

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  4. Ketones are generally less reactive than Aldehydes in nucleophilic add...

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  5. Acetic acid associates as dimers in benzene. What is the Van’t Hoff fa...

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  6. The pH of a 2 M solution of a weak monobasic acid (HA) is 4. What is t...

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  7. In the given reaction, product formed is CH3CHO+HCN⟶CH3CH(OH)CN

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  12. What is the standard reduction potential of the cathode of a galvanic ...

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  13. What is the EMF of a galvanic cell if the standard reduction potential...

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  14. Who invented the galvanic cell?

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  16. What is the EMF of a galvanic cell if the standard oxidation potential...

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