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The ratio of diameters of molecules of t...

The ratio of diameters of molecules of the two gases is 3:5 and their mean free path of the molecule is in the ratio of 5:3 then the ratio of number density of the two gases is

A

`5:3`

B

`25:9`

C

`9:25`

D

`1:1`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the ratio of the number densities of two gases given the ratio of their molecular diameters and mean free paths. ### Step-by-Step Solution: 1. **Identify Given Ratios**: - Let the diameter of the first gas be \( d_1 \) and the second gas be \( d_2 \). We are given: \[ \frac{d_1}{d_2} = \frac{3}{5} \] - Let the mean free path of the first gas be \( \lambda_1 \) and the second gas be \( \lambda_2 \). We are given: \[ \frac{\lambda_1}{\lambda_2} = \frac{5}{3} \] 2. **Mean Free Path Formula**: - The mean free path \( \lambda \) is given by the formula: \[ \lambda = \frac{1}{\sqrt{2} \pi d^2 n} \] - Where \( n \) is the number density. 3. **Setting Up Equations**: - For the first gas: \[ \lambda_1 = \frac{1}{\sqrt{2} \pi d_1^2 n_1} \] - For the second gas: \[ \lambda_2 = \frac{1}{\sqrt{2} \pi d_2^2 n_2} \] 4. **Forming a Ratio**: - Taking the ratio of \( \lambda_1 \) to \( \lambda_2 \): \[ \frac{\lambda_1}{\lambda_2} = \frac{\frac{1}{\sqrt{2} \pi d_1^2 n_1}}{\frac{1}{\sqrt{2} \pi d_2^2 n_2}} = \frac{d_2^2 n_2}{d_1^2 n_1} \] 5. **Substituting Known Ratios**: - From the problem, we know: \[ \frac{\lambda_1}{\lambda_2} = \frac{5}{3} \] - Therefore, we can write: \[ \frac{5}{3} = \frac{d_2^2 n_2}{d_1^2 n_1} \] 6. **Substituting Diameter Ratio**: - We know \( \frac{d_1}{d_2} = \frac{3}{5} \), so: \[ \frac{d_2}{d_1} = \frac{5}{3} \] - Squaring this gives: \[ \frac{d_2^2}{d_1^2} = \left(\frac{5}{3}\right)^2 = \frac{25}{9} \] 7. **Setting Up the Equation**: - Substitute \( \frac{d_2^2}{d_1^2} \) into the equation: \[ \frac{5}{3} = \frac{25}{9} \cdot \frac{n_2}{n_1} \] 8. **Solving for the Density Ratio**: - Rearranging gives: \[ \frac{n_2}{n_1} = \frac{5}{3} \cdot \frac{9}{25} = \frac{45}{75} = \frac{3}{5} \] - Therefore: \[ \frac{n_1}{n_2} = \frac{5}{3} \] 9. **Final Ratio**: - Thus, the ratio of number densities of the two gases is: \[ n_1 : n_2 = 5 : 3 \] ### Conclusion: The ratio of the number density of the two gases is \( 5 : 3 \).
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