OXYMERCURATION-DEMERCURATION METHOD:

OXYMERCURATION-DEMERCURATION MECHANISM

Method OF Preparation OF Alcohol by Acidic Hydration OF Alkene || OMDM (Oxymercuration and Demercuration) OF Alkenes || Kucherov Reaction

Oxymercuration-Demercuration (OMDM) reaction

Preparation OF Alcohol and Ether by Acidic Hydration || Oxymercuration Demercuration reaction || Hydroboration oxidation || Reaction OF R-X with HOH and NaOH ( by SN-Reaction )

Methods OF Preparation OF Alcohol | | Oxymercuration and Demercuration Reaction | | Kucherov reaction

Reaction Mechanism : Reaction Mechanism : 1) oxymercuration/demercuration 2) hydroboration/oxidation 3) kucherov reaction

Addition of mercuric acetate in the presence of water is called as oxymercuration.The adduct obtained gives alcohol on reduction with NaBH_4 in alkaline medium.This is known as demercuration.Oxymercuration demercuration allows Markownikoff's addition of H, OH without rearrangement.The net result is the addition of H_2O Answer the following question : CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)(C)-CH=CH_2underset((ii)CH_3OH NaBH_4NaOH)overset((i)Hg(OAc)_2.THF)toAoverset(HI(Conc.))toB Product B is :