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Detection of elements like nitrogen, hal...

Detection of elements like nitrogen, halogens and sulphur are done using Lassigne's test. Discuss the chemistry of Lassigne's test for the above elements

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Write the chemical equations involved in the detection of N, halogen and sulphur present in an organic compound by Lassaigne's test.

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Justify the following statements. i. Water mixed with formic acid cannot be separated by fractional distillation. ii. o -nitrophenol is steam volatile while p-nitrophenol is not. iii. Freshly prepared FeSO_4 solution is insisted during the test for nitrogen in Lassaignes test. iv. Copper spiral is used in the apparatus for Dumas method.

V PUBLICATION-ORGANIC CHEMISTRY SOME BASIC PRINCIPLES AND TECHNIQUES-QUESTION BANK
  1. Describe the method which can be used to separate two compounds with d...

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  2. What is the difference between distillation, dístillation under reduce...

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  3. Detection of elements like nitrogen, halogens and sulphur are done usi...

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  4. Give the principle of estimation of nitrogen by Dumas method.

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  5. What is chromatography?

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  6. Expain the reason for the fusion of an organic compound with metallic ...

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  7. Name a suitable method for separation of components from a mixture of ...

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  8. An organic compound contains 69% carbon and 4.8% hydrogen and the rema...

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  9. A sample of 0.50 g of an organic compound was treated according to Kje...

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  10. 0.3780 g an organic compound gave 0.5740 g AgCl in Carius method. Calc...

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  11. In Carius method 0.468 g of a compound afforded 0.668 g barium sulphat...

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  12. The best and latest technique for isolation, purification and separati...

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  13. Indicate the sigma and pi bonds in the following molecules : C6 H6, C6...

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  14. Draw the resonance structures for the following compounds. Show the el...

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  15. Explain 'Inductive effect' and electomeric effect. Which electron disp...

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  16. Discuss the principle of estimation of halogens, sulphur and phosphoru...

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  17. Why is nitric acid added to sodium extract before adding silver nitrat...

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  18. Explain why an organic liquid vapourises at a temperature below its bo...

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  19. In the organic compound CH2=CH-CH2-CH2-C -= CH, the pair of hybridised...

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  20. Fill up the balnk. In Lassaigne's test for N, Prussian blue colour is ...

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