Home
Class 12
CHEMISTRY
A first order reạction takes 40 min for ...

A first order reạction takes 40 min for 30 % decomposition. Calculate `t^(1 / 2)`

Text Solution

Verified by Experts

`(t)=(2.303)(k) log ([(A)]_(0))([(A)])` `[(A)]_(0)=100 ,[(A)]=100-30=70``40 doteq (2.303)(k) log ([100])([70])` `40=(2.303)(k) * 0.1549 `40=(0.35673)(k)` `(k)=(0.35673)(40)=89.1 * 10^(-3)` &`therefore t_(1/2)=(0.693)(k)=(0.693)(8.91 xx 10^(-3))=77.70 (min)^(-1)`
Promotional Banner

Topper's Solved these Questions

  • BIOMOLECULES

    V PUBLICATION|Exercise QUESTION BANK|99 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    V PUBLICATION|Exercise QUESTION BANK|74 Videos

Similar Questions

Explore conceptually related problems

The decomposition of N_(2)O_(5) according to the equation, 2N_(2)O_(5) (g) rarr 4NO_(2) (g) + O_(2) (g) is a first order reaction, After 30 minutes from the start of the decomposition in a closed vessel, the total pressure developed is found to be 284.5 mm Hg and on completion, the total pressure is 584.5 mm Hg. Calculate the rate constant of the reaction.

A 1st order reaction takes 69.3 minutes for 50 %completion. Derive an equation for determining the time needed for 80 % completion of this reaction.

A first order reaction is 20% complete in 10 min. Calculate the specific rate constant of the reaction.

A first order reaction is 20% complete in ten minutes. Calculate time taken for the reaction to go upto 75% completion.

A first order reaction is 20% complete in 5 minutes. Calculate the time taken for the reaction to be 60% complete

A first order reaction has rate constant of 10^(-2) (sec)^(-1) . Calculate the half life period for this reaction.

For a first order reaction, show that time required for 99 % completion is twice the time required for the completion of 90 % of reaction.

V PUBLICATION-CHEMICAL KINETICS-Question Bank
  1. During nuclear explosion, one of the products is 90{Sr} with half-life...

    Text Solution

    |

  2. For a first order reaction, show that time required for 99 % completio...

    Text Solution

    |

  3. A first order reạction takes 40 min for 30 % decomposition. Calculate ...

    Text Solution

    |

  4. For the decomposition of azoisopropane to hexane and nitroger at 543 K...

    Text Solution

    |

  5. The following data were obtained during the first order thermal decomp...

    Text Solution

    |

  6. The rate constant for the decomposition of (N)(2) (O)(5) at various te...

    Text Solution

    |

  7. The rate constant for the decomposition of hydrocarbons is 2.418 x 10^...

    Text Solution

    |

  8. Consider a certain reaction ArarrProducts with k=2.0 xx 10^(-2) (s)^(...

    Text Solution

    |

  9. Sucrose decomposes in acid solution into glucose and fructose accordin...

    Text Solution

    |

  10. The decomposition of hydrocarbon follows the equationk=(4.5xx10^11s^-1...

    Text Solution

    |

  11. The rate constant for the first order decomposition of (H)(2) (O)(2) i...

    Text Solution

    |

  12. The decomposition of A into product has value of k as 4.5 × 103 s1 at ...

    Text Solution

    |

  13. The time required for 10 % completion of a first order reaction at 298...

    Text Solution

    |

  14. The rate of a reaction quadruples when the temperature changes from 29...

    Text Solution

    |

  15. The half-life for radioactive decay of 14{C} is 5730 years. An archaeo...

    Text Solution

    |

  16. For the reaction 3NO(g)toNO2(g)+NO(g),Rate=k[NO]^2.What is the order o...

    Text Solution

    |

  17. Some statements related to kinetic are given below.The number of react...

    Text Solution

    |

  18. "A complex reaction consists of a number of steps. The overall rate of...

    Text Solution

    |

  19. "Activation energies are low for fast reaction and high for slow react...

    Text Solution

    |

  20. Assuming that energy of activation for most of the reactions is 52 (kJ...

    Text Solution

    |