Home
Class 12
CHEMISTRY
K2PTCl6' is a well known compound while ...

K2PTCl6' is a well known compound while the corresponding nickel salt is unknown?

Text Solution

Verified by Experts

The oxidation state of .(Pt). in .(K)_(2) (P) (CCl)_(6). is .+4 .. Thermodynamic stability of compounds of transition metals can be evaluated-in terms of the magnitude of ionisation enthalpies of the metals, Smaller the ionisation energy of the metal Stabler is its compound. The sum of Ist four ionisation enthatpies of Pt is less than that, of Ni. Hence .(K)_(2) (PtCl)_(6). is known whereas corresponding Ni compoünd is unknown.
Promotional Banner

Topper's Solved these Questions

  • SURFACE CHEMISTRY

    V PUBLICATION|Exercise QUESTION BANK|126 Videos
  • The p-BLOCK ELEMENTS

    V PUBLICATION|Exercise QUESTION BANK|147 Videos

Similar Questions

Explore conceptually related problems

Statement 1 : Xenon fluorides are well known and stable but the corresponding chlorides have not been reported. Statement 2: Xe-F bond is more strong than Xe-Cl bond and F_2 molecule has low bond dissociation energy than that of Cl_2 molecule.

Assertion : Xenon fluorides are well known and stable but the corresponding chlorides have not been reported. Reason : Xe-F bond is more strong than Xe-Cl bond and F_2 molecule has low bond dissociation energy than that of Cl_2 molecule.

Each rubidium halide crystallizing in the NaCl type lattice has a unit cell length 30 pm greater than for corresponding potassium salt ( r_(k)=133 pm) of the same halogen. What is the ionic radius of Rb^(+) ?

Saline hydrides are known to react with water violently producing fire. Can CO_2 a well known fire extinguisher be used in this case? Explain.

V PUBLICATION-THE d- AND f- BLOCK ELEMENTS-QUESTION BANK
  1. Manganese and technetium have very low melting points. Why?

    Text Solution

    |

  2. Name the transition element with highest density?

    Text Solution

    |

  3. K2PTCl6' is a well known compound while the corresponding nickel salt ...

    Text Solution

    |

  4. Copper cannot liberate (H)(2). from acids. Why?

    Text Solution

    |

  5. Copper is the onty elemerit in the 1st transition series with a posit...

    Text Solution

    |

  6. All the bonds between manganese and oxygen in '(KMnO4 are covalent. Wh...

    Text Solution

    |

  7. Which is the highest oxidation state shown by any transition mètal?

    Text Solution

    |

  8. Cr(2)O(7)^(2-) is a strong oxidising agent whereas MoO(3) and WO(3) ar...

    Text Solution

    |

  9. Highest fluoride of Mn is MnF(4), whereas highest oxide is Mn(2)O(7) ....

    Text Solution

    |

  10. Draw the structure of Mn(2) O(7) ?

    Text Solution

    |

  11. Name the catnlyst used in (i) the manufacture of sulphuric acid by con...

    Text Solution

    |

  12. Name the catalyst used in i) the oxidation of ammonia to nitric acid b...

    Text Solution

    |

  13. Transition elements act as catalysts. Why?

    Text Solution

    |

  14. Why the transition metal compounds are coloured?

    Text Solution

    |

  15. Give the spin only formula fór calculating the magnetic moment of a tr...

    Text Solution

    |

  16. Name the ores of Titanium?

    Text Solution

    |

  17. . Name the metal, with highest melting point?

    Text Solution

    |

  18. Name the common ores of i) Chromiüm ii) Molybdenum iii) Tungsten

    Text Solution

    |

  19. How is potassium permanganate prepared in the laboratory?

    Text Solution

    |

  20. What is the reaction between KMnO(4) and sodium thiosulphate?

    Text Solution

    |